2. (a) What is partition function? Obtain a general relation of function with the following the partition thermodynamics functions: i) Internal Energy ii) Entropy for N indistinguishable particles. (b) Using a rigid rotor model, derive rotational partition function in the limit of high temperature.

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter18: More Statistical Thermodynamics
Section: Chapter Questions
Problem 18.4E
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2. (a) What is partition function? Obtain a general relation of
function with the following
thermodynamics functions:
the partition
i) Internal Energy
ii) Entropy for N indistinguishable particles.
(b) Using a rigid rotor model, derive rotational partition
function in the limit of high temperature.
Transcribed Image Text:2. (a) What is partition function? Obtain a general relation of function with the following thermodynamics functions: the partition i) Internal Energy ii) Entropy for N indistinguishable particles. (b) Using a rigid rotor model, derive rotational partition function in the limit of high temperature.
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ISBN:
9781133958437
Author:
Ball, David W. (david Warren), BAER, Tomas
Publisher:
Wadsworth Cengage Learning,