2. (a) Predict the products of the following reactions with mechanism : to DCC Ti) H3C- -COOH →? DMAP + 'Ph-OH CH3 (i CH3¬Ċ=CH2CI- Gilman rcagent →? BF,
2. (a) Predict the products of the following reactions with mechanism : to DCC Ti) H3C- -COOH →? DMAP + 'Ph-OH CH3 (i CH3¬Ċ=CH2CI- Gilman rcagent →? BF,
Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions
Section30.SE: Something Extra
Problem 41AP: In light of your answer to Problem 30-40, explain why a mixture of products occurs in the following...
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( do 1 and ii
![2. (a) Predict the products of the following
reactions with mechanism :
to
Ti) H3C-
-COOH
DCC
→ ?
DMAP
Ph-OH
CH3
(ii) CH3-C=CH2C1-
Gilman rcagent
→?
BF,
1 1) LDA
2) CH31
-78 °C
1) LIAIH,
S(iv) Ph-COOEt
→ ?
2) H30®
1) Bu,CuLi
-→ ?
2) Mel
3) NH,CI, HạO](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F67219728-edf3-4096-8101-0cd41ba15d38%2F6153e62f-4b7d-4163-8e6d-7c77fdf1152a%2Fo1ih7yf_processed.png&w=3840&q=75)
Transcribed Image Text:2. (a) Predict the products of the following
reactions with mechanism :
to
Ti) H3C-
-COOH
DCC
→ ?
DMAP
Ph-OH
CH3
(ii) CH3-C=CH2C1-
Gilman rcagent
→?
BF,
1 1) LDA
2) CH31
-78 °C
1) LIAIH,
S(iv) Ph-COOEt
→ ?
2) H30®
1) Bu,CuLi
-→ ?
2) Mel
3) NH,CI, HạO
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