2. (a) A sample of 1 mole ammonia at 14 atm and 25 °C in a cylinder fitted with a moveable piston expands against a constant external pressure of 1.00 atm. At equilibrium, the pressure and volume of the gas are 1.00 atm and 23.5 L respectively. The specific heat of ammonia is 0.0258 Jg1 K-1. (i) Write the expression for finding q and w for the above processes, in the question what do you know and what do you need to find? (ii) Calculate the q, w and AU for the process.

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2.
(a) A sample of 1 mole ammonia at 14 atm and 25 °C in a cylinder fitted with a moveable piston
expands against a constant external pressure of 1.00 atm. At equilibrium, the pressure and
volume of the gas are 1.00 atm and 23.5 L respectively. The specific heat of ammonia is 0.0258
Jg1 K-1.
(i)
Write the expression for finding q and w for the above processes, in the question
what do you know and what do you need to find?
(ii)
Calculate the q, w and AU for the process.
Transcribed Image Text:2. (a) A sample of 1 mole ammonia at 14 atm and 25 °C in a cylinder fitted with a moveable piston expands against a constant external pressure of 1.00 atm. At equilibrium, the pressure and volume of the gas are 1.00 atm and 23.5 L respectively. The specific heat of ammonia is 0.0258 Jg1 K-1. (i) Write the expression for finding q and w for the above processes, in the question what do you know and what do you need to find? (ii) Calculate the q, w and AU for the process.
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