2 ClO2(aq) + 2 OH (aq) → ClO3°(aq) + CIO2°(aq) + H201) [CI02]o (mol/L) [ОН 10 (mol/ L) Initial Rate (mol/L*s) 0.150 0.200 5.75 x 10-2 0.300 0.200 2.30 x 10-1 0.300 0.100 1.15 х 10-1 а. Determine the rate law and the value of the rate constant b. What would the initial rate be for an experiment with [CIO2]o = 0.350 mol/L and [OH-]o = 0.169 mol/L? %3D

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
icon
Concept explainers
Question

The following data were obtained for the reaction:

### Reaction and Experimental Data

The chemical reaction under study is:

\[ 2 \text{ClO}_2(aq) + 2 \text{OH}^-(aq) \rightarrow \text{ClO}_3^-(aq) + \text{ClO}_2^-(aq) + \text{H}_2\text{O}(l) \]

#### Experimental Data Table:

| \([\text{ClO}_2]_0\) (mol/L) | \([\text{OH}^-]_0\) (mol/L) | Initial Rate (mol/L\*s) |
|------------------------------|-----------------------------|-------------------------|
| 0.150                        | 0.200                       | \(5.75 \times 10^{-2}\)  |
| 0.300                        | 0.200                       | \(2.30 \times 10^{-1}\)  |
| 0.300                        | 0.100                       | \(1.15 \times 10^{-1}\)  |

### Problems to Solve:

a. **Determine the rate law and the value of the rate constant.**

b. **Calculate the initial rate for an experiment with \([\text{ClO}_2]_0 = 0.350 \, \text{mol/L}\) and \([\text{OH}^-]_0 = 0.169 \, \text{mol/L}\).**

### Explanation of the Table:

The table presents the initial concentrations of the reactants, \([\text{ClO}_2]_0\) and \([\text{OH}^-]_0\), along with the observed initial reaction rates. This data is used to determine the reaction's rate law, which explains how the reaction rate depends on the concentration of reactants. By analyzing the changes in concentration and corresponding rates, one can deduce the order of the reaction for each reactant and calculate the rate constant.
Transcribed Image Text:### Reaction and Experimental Data The chemical reaction under study is: \[ 2 \text{ClO}_2(aq) + 2 \text{OH}^-(aq) \rightarrow \text{ClO}_3^-(aq) + \text{ClO}_2^-(aq) + \text{H}_2\text{O}(l) \] #### Experimental Data Table: | \([\text{ClO}_2]_0\) (mol/L) | \([\text{OH}^-]_0\) (mol/L) | Initial Rate (mol/L\*s) | |------------------------------|-----------------------------|-------------------------| | 0.150 | 0.200 | \(5.75 \times 10^{-2}\) | | 0.300 | 0.200 | \(2.30 \times 10^{-1}\) | | 0.300 | 0.100 | \(1.15 \times 10^{-1}\) | ### Problems to Solve: a. **Determine the rate law and the value of the rate constant.** b. **Calculate the initial rate for an experiment with \([\text{ClO}_2]_0 = 0.350 \, \text{mol/L}\) and \([\text{OH}^-]_0 = 0.169 \, \text{mol/L}\).** ### Explanation of the Table: The table presents the initial concentrations of the reactants, \([\text{ClO}_2]_0\) and \([\text{OH}^-]_0\), along with the observed initial reaction rates. This data is used to determine the reaction's rate law, which explains how the reaction rate depends on the concentration of reactants. By analyzing the changes in concentration and corresponding rates, one can deduce the order of the reaction for each reactant and calculate the rate constant.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps

Blurred answer
Knowledge Booster
Catalysis and Enzymatic Reactions
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY