ADVANCED STUDY ASSIGNMENT 1. 0.500 g of Ca is added to 50.0 mL of 1.0 M HCI. Once reaction is complete, the temperature of the solution has risen from 25.2 °C to 71.4 °C. The reaction proceeds by the following equation: Cа (8) + 2 H'(аq) — Са"(аq) + H(g) Calculate the heat gained by the solution q= mos•AT, where s = 4.184 J/g•°C m = mass in grams s- specific heat in J/g• °C AT = final temp. - initial temp. Fsoln = oin= kJ b. Heat lost by the reaction: q.xn = -quoln kJ AH kJ/mol Ca Calculate the heat of reaction:
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
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Exp 10B Second Lab.pdf
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Experiment 52
Name
Section
ADVANCED STUDY ASSIGNMENT
1. 0.500 g of Ca is added to 50.0 mL of 1.0 M HCI. Once reaction is complete, the temperature of the
solution has risen from 25.2 °C to 71.4 °C. The reaction proceeds by the following equation:
Са (s) + 2 H'(аq) —> Са" (аq) + H(g)
Calculate the heat gained by the solution
q = m•s•AT, where s = 4.184 J/%•°C
m = mass in grams
s = specific heat in J/g• °C
AT = final temp. - initial temp.
a.
9soln =
soin =
kJ
kJ
b.
Heat lost by the reaction: q;xn = -qsoln
Calculate the heat of reaction:
AH° =
kJ/mol Ca
c.
2. Using Hess' Law, calculate the enthalpy of formation for C,Hg (g) using the following thermodynamic
data.
C(s) + O2(g) → CO2(g)
AH° =-393.5 kJ/mol
H2(g) + ½O(g) → H,O(1)
AH° = -285.8 kJ/mol
C3Hs(g) + 502(g) → 3CO2(g) + 4H;O(1)
AH° = =2199.0 kJ/mol
277](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F6e109467-0d83-4f4d-b5f6-71f4292ccbcd%2Fb65aeff1-f41c-48da-9850-4c7a9ed508c4%2Fw19pfvs_processed.png&w=3840&q=75)
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f Data - CHЕМ 1112 Exp 10B.pdf
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ENT 10.B Enthalpy
PART B
Heat of Reaction of Mg(s) + HCl(aq)
Initial temperature of HCI solution
22. 2c
Mass of magnesium
Moles of magnesium
moles
Highest temperature of mixture
61.6
°C
AT of mixture
°C
Heat gained by the solution
J
Heat lost by the reaction
J
Heat of reaction per mole of magnesium
J/mole Mg
Heat of reaction per mole of magnesium
kJ/mole Mg
Heat of Reaction of MgO(s) + HCI(aq)
_22.0
1,011 8
Initial temperature of HCI solution
°C
Mass of magnesium oxide
Moles of magnesium oxide
moles
Highest temperature of mixture
36.9
°C
AT of mixture
°C
Heat gained by the solution
J
Heat lost by the reaction
Heat of reaction per mole of magnesium oxide
J/mole MgO
Heat of reaction per mole of magnesium oxide
kJ/mole MgO
Heat of reaction of water
-285.9
kJ/mole H;0
Heat of reaction per mole of magnesium
(from previous section)
kJ/mole Mg
AH,MgO(s)
kJ/mole MgO
AH,MgO(s)
(Textbook value, if available, for comparison]
kJ/mole MgO
132](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F6e109467-0d83-4f4d-b5f6-71f4292ccbcd%2Fb65aeff1-f41c-48da-9850-4c7a9ed508c4%2F3j56wcj_processed.png&w=3840&q=75)
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