· 1s, (c) Is → 3d, 3s? In view of this (a) Is 2s, (b) 2p – (d) 3d 4f, (e) 4d - selection rule, explain why it is possible to observe the various emission series shown in Figure 6.11.

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6.113 When an electron makes a transition between energy
levels of a hydrogen atom, there are no restrictions on
the initial and final values of the principal quantum
number n. However, there is a quantum mechanical
rule that restricts the initial and final values of the
orbital angular momentum l. This is the selection
rule, which states that Δl = ±1; that is, in a
transition, the value of l can only increase or decrease
by 1. According to this rule, which of the following
transitions are allowed:

· 1s, (c) Is → 3d,
3s? In view of this
(a) Is 2s, (b) 2p –
(d) 3d 4f, (e) 4d -
selection rule, explain why it is possible to observe
the various emission series shown in Figure 6.11.
Transcribed Image Text:· 1s, (c) Is → 3d, 3s? In view of this (a) Is 2s, (b) 2p – (d) 3d 4f, (e) 4d - selection rule, explain why it is possible to observe the various emission series shown in Figure 6.11.
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