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Use the figure below to answer the following: a) Determine the energy difference between the 6s and 5p states, as well as the energy difference between the 4d and 5p states and between the 6s and 4d states.

Use the figure below to answer the following: a) Determine the energy difference between the 6s and 5p states, as well as the energy difference between the 4d and 5p states and between the 6s and 4d states.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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4.32 3 N 9s 8s 7s 6s 5 s ²S112 100 6090 6911.3- -12,434 12,523 4044.11 7664.1- ²P312 7699.0 ²P 1/2 4047.2- 6965.0 11.771.7 ²D 5/2, 3/2 6d. 5d 4 d 6936.0 11,689.8- 1 5f ²F 7/2,5/2 15,166.3- 1
Transcribed Image Text:4.32 3 N 9s 8s 7s 6s 5 s ²S112 100 6090 6911.3- -12,434 12,523 4044.11 7664.1- ²P312 7699.0 ²P 1/2 4047.2- 6965.0 11.771.7 ²D 5/2, 3/2 6d. 5d 4 d 6936.0 11,689.8- 1 5f ²F 7/2,5/2 15,166.3- 1
Use the figure below to answer the following: a) Determine the energy difference between the 6s and 5p states, as well as the energy difference between the 4d and 5p states and between the 6s and 4d states. (b) The transitions from (4d to 5p) and (4d to 5s) are allowed, respectively. Why? (c) What are the four selection rules, including the four atomic quantum numbers, in general for an electronic transition involving the emission or absorption of a photon for an atom? (d) What are the energies of the 5p, 6s, and 4d levels now that it is known that the 4s level is really at -4.34 eV rather than 0 eV? -In the following Figure. Potassium transitions with wavelength labels in A' (angstrom). The ground state has been skewed to read zero eV, as you can see. Actually, the ground state is at -4.34 eV.
Transcribed Image Text:Use the figure below to answer the following: a) Determine the energy difference between the 6s and 5p states, as well as the energy difference between the 4d and 5p states and between the 6s and 4d states. (b) The transitions from (4d to 5p) and (4d to 5s) are allowed, respectively. Why? (c) What are the four selection rules, including the four atomic quantum numbers, in general for an electronic transition involving the emission or absorption of a photon for an atom? (d) What are the energies of the 5p, 6s, and 4d levels now that it is known that the 4s level is really at -4.34 eV rather than 0 eV? -In the following Figure. Potassium transitions with wavelength labels in A' (angstrom). The ground state has been skewed to read zero eV, as you can see. Actually, the ground state is at -4.34 eV.
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