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- 16.42 Draw the products formed when each compound is treated with CH3CH₂COCI, AICI 3. a. b. C. N Z-I16.13 Name each of the following amines by one of the methods used in Exercises 16.7, 16.9, and 16.11: a. CH₁₂ CH-C-NH, C. NH, CH₁₂ b. CH,CH,-N-CH₂CH, d. Cl CH, NH CH,CHCH,CHCH,19.57 Because phenol (C6H5OH) is less acidic than a carboxylic acid, it can be deprotonated by NaOH but not by the weaker base NaHCO3. Using this information, write out an extraction sequence that can be used to separate C6H5OH, benzoic acid, and cyclohexanol. Show what compound is present in each layer at each stage of the process, and if it is present in its neutral or ionic form.
- Draw the product formed when phenylacetic acid (C6H5CH2COOH) is treated with each reagent. With some reagents, no reaction occurs. (A - F)Explain step by step how did the compounds derived to their IUPAC name for letter b,f,h,k and l only.17. Rank the acid derivatives with respect to their reactivity with water. acid halide > ester > acid anhydride > amide acid anhydride > amide > acid halide > ester amide > ester > acid anhydride > acid halide acid halide > acid anhydride > ester > amide A) B) C) D) 18. Disregarding A) 3 stereoisomers, how many different enols can the B-diketone CH3COCH₂COCH₂CH3 form? B) 1 C) 4 D) O E) 2
- Suppose you have a mixture of these three compounds. Devise a chemical procedure based on their relative acidity or basicity to separate and isolate each in pure form.Chemistry Common Names of Benzene Derivatives LOCH 3 CH3 Styrene Anisole Toluene Practices 17.1, 17.5 P. 793; 17.24, 17.25 P. 822 Examples: Name the following compounds. OH A H D OMe CI O₂N LOH OCH 3 B Br- H3C- OH CO₂H OMe E CH3 o-xylene CH3 CI Br Br OH m-cresol CI C CH3 NH₂ F CH3 CI OHa. b. 22.16 Using ammonia as your source of nitrogen, show the reagents you would use to prepare each of the following amines: C. d. e. O f. PRACTICE the skill H Answer xi -N -NH₂ H O 1) [H*] NaBH₂CN NH3 2) [H*] NaBH3CN CH3CHO