19. What conditions given below would you predict to generate the highest amounts of the product shown? First choice: Second choice: OTS Conditions? (a) NaOMe in MeOH. (b) NaSMe in MeOH. (c) LDA in THF (d) NaSMe in DMF
19. What conditions given below would you predict to generate the highest amounts of the product shown? First choice: Second choice: OTS Conditions? (a) NaOMe in MeOH. (b) NaSMe in MeOH. (c) LDA in THF (d) NaSMe in DMF
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![**Question 19:**
*What conditions given below would you predict to generate the highest amounts of the product shown?*
[Reaction Scheme: A cyclohexane ring with an OTosylate (OTs) group is converted to a cyclohexene with a double bond. The reaction conditions are questioned.]
(a) NaOMe in MeOH.
(b) NaSMe in MeOH.
(c) LDA in THF.
(d) NaSMe in DMF.
**Answer:**
- **First choice: ______**
- **Second choice: ______**
**Explanation of Diagrams:**
There are two chemical structures displayed. The first structure is a cyclohexane ring with a tosylate group (OTs) attached. This indicates that a substitution reaction or elimination process may be used to convert this compound into the second structure.
The second structure is a cyclohexene, showing that a double bond is present, suggesting the product of an elimination reaction leading to an alkene.
The task is to select the best conditions from the options provided that would favor the formation of the cyclohexene product. The options represent different base and solvent conditions that could potentially drive an elimination reaction.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F4c8d4003-6dbe-4a96-8cef-3ca09402ad71%2Fa86e501a-14f7-4015-8c71-7b4b4579a17f%2Fkdiqlh_processed.png&w=3840&q=75)
Transcribed Image Text:**Question 19:**
*What conditions given below would you predict to generate the highest amounts of the product shown?*
[Reaction Scheme: A cyclohexane ring with an OTosylate (OTs) group is converted to a cyclohexene with a double bond. The reaction conditions are questioned.]
(a) NaOMe in MeOH.
(b) NaSMe in MeOH.
(c) LDA in THF.
(d) NaSMe in DMF.
**Answer:**
- **First choice: ______**
- **Second choice: ______**
**Explanation of Diagrams:**
There are two chemical structures displayed. The first structure is a cyclohexane ring with a tosylate group (OTs) attached. This indicates that a substitution reaction or elimination process may be used to convert this compound into the second structure.
The second structure is a cyclohexene, showing that a double bond is present, suggesting the product of an elimination reaction leading to an alkene.
The task is to select the best conditions from the options provided that would favor the formation of the cyclohexene product. The options represent different base and solvent conditions that could potentially drive an elimination reaction.
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