16.28 Phosgene is a toxic gas prepared by the reaction of carbon monoxide with chlorine: CO(g) + Cl,(g) COC»(g) These data were obtained in a kinetics study of its formation: Initial [CO] (mol/L) Initial [Cl,] (mol/L) Initial Rate Experiment (mol/L•s) 1.29×10–29 1.33×10-30 1.30X10–29 1.32×10-31 1 1.00 0.100 0.100 0.100 0.100 3 1.00 4 0.100 0.0100 (a) Write the rate law for the formation of phosgene. (b) Calculate the average value of the rate constant.

16.28 Phosgene is a toxic gas prepared by the reaction of carbon monoxide with chlorine: CO(g) + Cl,(g) COC»(g) These data were obtained in a kinetics study of its formation: Initial [CO] (mol/L) Initial [Cl,] (mol/L) Initial Rate Experiment (mol/L•s) 1.29×10–29 1.33×10-30 1.30X10–29 1.32×10-31 1 1.00 0.100 0.100 0.100 0.100 3 1.00 4 0.100 0.0100 (a) Write the rate law for the formation of phosgene. (b) Calculate the average value of the rate constant.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

16.28 Phosgene is a toxic gas prepared by the reaction of carbon
monoxide with chlorine:
CO(g) + Cl,(g)
COC»(g)
These data were obtained in a kinetics study of its formation:
Initial [CO]
(mol/L)
Initial [Cl,]
(mol/L)
Initial Rate
Experiment
(mol/L•s)
1.29×10–29
1.33×10-30
1.30X10–29
1.32×10-31
1
1.00
0.100
0.100
0.100
0.100
3
1.00
4
0.100
0.0100
(a) Write the rate law for the formation of phosgene.
(b) Calculate the average value of the rate constant.

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