16. The reaction of an aldehyde with hydrogen cyanide is an example of reaction. a nucleophilic substitution a. b. an electrophilic addition an electrophilic substitution с. d. a nucleophilic addition 17. Identify the electrophile in the reaction of benzaldehyde with hydrogen cyanide. 18. Choose the BEST reagent for carrying out each of the following conversions. CH,OH H. . NABH4, ethanol p. CH2PPH3 =. NAOH, H20 1. All of the above

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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the
Cyanohydrins are important intermediates in the synthesis of a-hydroxycarboxylic acids from ketones and
aldehydes. The nitrile functional group can be hydrolyzed by aqueous acid to yield a carboxylic acid. Nitriles can
also be hydrolyzed to carboxylic acids using aqueous base. Unfortunately, when a cyanohydrin is treated with
aqueous base the original carbonyl compound is isolated.
OH
CH- COOH
HO
CN
H30*
H.
H.
HC=N
NAOH
H20
H
cyamhydnin
+ NACN + HO
16. The reaction of an aldehyde with hydrogen cyanide is an example of
reaction.
a nucleophilic substitution
a.
b.
an electrophilic addition
с.
an electrophilic substitution
d.
a nucleophilic addition
17. Identify the electrophile in the reaction of benzaldehyde with hydrogen cyanide.
18. Choose the BEST reagent for carrying out each of the following conversions.
CH,OH
H.
1. NABH4,
ethanol
p. CH2PPH3
=. NAOH, H20
. All of the above
Transcribed Image Text:2 questions: the Cyanohydrins are important intermediates in the synthesis of a-hydroxycarboxylic acids from ketones and aldehydes. The nitrile functional group can be hydrolyzed by aqueous acid to yield a carboxylic acid. Nitriles can also be hydrolyzed to carboxylic acids using aqueous base. Unfortunately, when a cyanohydrin is treated with aqueous base the original carbonyl compound is isolated. OH CH- COOH HO CN H30* H. H. HC=N NAOH H20 H cyamhydnin + NACN + HO 16. The reaction of an aldehyde with hydrogen cyanide is an example of reaction. a nucleophilic substitution a. b. an electrophilic addition с. an electrophilic substitution d. a nucleophilic addition 17. Identify the electrophile in the reaction of benzaldehyde with hydrogen cyanide. 18. Choose the BEST reagent for carrying out each of the following conversions. CH,OH H. 1. NABH4, ethanol p. CH2PPH3 =. NAOH, H20 . All of the above
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