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Answered: 16. Provide a curved arrow mechanism…

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Chemistry

16. Provide a curved arrow mechanism for the following transformation. Be sure to rationalize the stereochemistry.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Which of the following is a limitation of the Friedel-Crafts reaction? Select one: O A. The carbocation electrophile can potentially undergo an unwanted rearrangement prior to its bonding to the aromatic ring. OB. Poly-alkylation products form when aromatic reactant and alkylating agent are mixed together in comparable amounts. OC. A Friedel-Crafts reaction fails when the aromatic starting compound contains a moderately or strongly deactivating group. OD. All of the above choices are limitations of the Friedel-Crafts reaction.
. Identify the aromatic compound which cannot undergo the Friedel-Crafts reaction with CH3Cl/AlCl3.
Please don't provide handwrotten solution ....
1) a) Propose a detailed mechanism for the reaction of 2-bromo-2,3-dimethylbutane with sodium methoxide (NaOCH3), showing formation of the major product. Please include: 1) a perspective diagram of the substrate 2) a Newman projection 3) a perspective diagram illustration of the transition state 4) curved arrows, lone pairs, formal/partial charges etc. as appropriate Special Request: Please don't do anything with the spectator ion. b) Draw a simple ('flat,' no dashes/wedges required) Lewis diagram of the minor product. 1) Why is it minor? 2) How would you alter the reaction conditions given to favor the minor product?
15. a. Label the reactive features, highlight the most reactive one, then highlight what it needs. Also, state if the reaction will start to create a carbocation, carbon radical, or carbanion, or will cause loss of aromatic character. If a carbocation, carbon radical, or carbanion starts to develop, label where that will occur. (Z)-2-methylpenta-1,3-diene with HBr b. Use mechanism arrows to illustrate the reaction that occurs. c. If applicable, use stabilization resources to deal with the carbocation, carbon radical, or carbanion that starts to develop during the reaction, and draw the structure of any resonance-stabilized intermediate. d. Continue labeling and diagramming the reaction until you find the major stable product(s). e. Finally, state the stereochemistry of the major product(s) and use either Fisher projection or perspective formula representations to illustrate that stereochemistry.
Please answer this NEATLY, COMPLETELY, and CORRECTLY for an UPVOTE. What is the most stable carbocation below?
a,b-Unsaturated carbonyl compounds are susceptible to either 1,2 addition or 1,4 (Michael)addition. Give examples of nucleophiles that would favor each case and explain yourreasoning
Type 2 electrophilic addition reaction
1. would you expect the relative rate of SE2 reactions to be faster or slower if a molecule of chlorine is used instead of bromine? Explain your reasoning? 2. why is the first step in an electrophilic aromatic bromination so much more endothermic than the first step in an electrophilic addition of alkene?
15. Polar protic solvents favor substitution because A) the SN2 mechanism they are weakly slovationg and the nucleophile is able to react rapidly. B) they strongly solvate the nucleophile lowering activation energy for formation of the transition state in the SN2 mechanism. C) they weakly solvate the leaving group allowing rapid loss of the halide according to the Hammond postulate. D) they strongly solvate the leaving group stabilizing the transition state for SN1 reactions according to the Hammond postulate.
Please solve and explain?