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Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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10.
9. Which of the following structures, if flat, would be classified as aromatic/nonaromatic/antiaromatic?
A)
E)
B)
Circle the compound that is antiaromatic.
+
A) s
allow H
C)
NH
NH
B) sp
11. Which of the following undergoes SN2 reaction with sodium methoxide most rapidly?
A) PhCH₂Br
B) Ph3CBr
C) PhCH₂CH₂Br
D) PhBr
E) PhCH₂CH₂CH₂Br
12. Nitrogen's lone pair electrons occupy what type of orbital in pyridine?
C) sp2
D)
D) sp3
E) p
opylon 2017 ! U
13. The dichlorobis (triphenylphosphine)palladium (II) catalyst is commonly used in Suzuki coupling reactions. The
triphenylphosphine ligands are... (circle all correct answers)?
A. X-type B. L-type C. positively charged D. neutral E. negatively charged
14. Which of the following is an INCORRECT statement about the chlorination of benzene by Cl2 and FeCl3?
A) FeCl3 functions to increase the electrophilicity of Cl2.
B) Formation of the sigma complex is the rate-determining step of the mechanism.
C) The carbanion intermediate is resonance stabilized.
D) The final step of the mechanism is deprotonation of the sigma complex.
Transcribed Image Text:10. 9. Which of the following structures, if flat, would be classified as aromatic/nonaromatic/antiaromatic? A) E) B) Circle the compound that is antiaromatic. + A) s allow H C) NH NH B) sp 11. Which of the following undergoes SN2 reaction with sodium methoxide most rapidly? A) PhCH₂Br B) Ph3CBr C) PhCH₂CH₂Br D) PhBr E) PhCH₂CH₂CH₂Br 12. Nitrogen's lone pair electrons occupy what type of orbital in pyridine? C) sp2 D) D) sp3 E) p opylon 2017 ! U 13. The dichlorobis (triphenylphosphine)palladium (II) catalyst is commonly used in Suzuki coupling reactions. The triphenylphosphine ligands are... (circle all correct answers)? A. X-type B. L-type C. positively charged D. neutral E. negatively charged 14. Which of the following is an INCORRECT statement about the chlorination of benzene by Cl2 and FeCl3? A) FeCl3 functions to increase the electrophilicity of Cl2. B) Formation of the sigma complex is the rate-determining step of the mechanism. C) The carbanion intermediate is resonance stabilized. D) The final step of the mechanism is deprotonation of the sigma complex.
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