15. 2 Plot the vapour pressure data for a mixture of benzene (B) and ethanoic acid (E) given below and plot the vapour pressure / composition curve for the mixture at 5 0 \ deg C. Then confirm that Raoult's and Henry's laws are obeyed in the appropriate regions. Deduce the activities and activity coefficients of the components on the Raoult's law basis and then, taking B as the solute, its activity and activity coefficient on a Henry's law basis. Finally, evaluate the excess Gibbs energy of the mixture over the composition range spanned by the data. 0 . 0 1 600.0439XE

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15. 2 Plot the vapour pressure data for a mixture of benzene (B) and ethanoic acid (E) given below
and plot the vapour pressure / composition curve for the mixture at 5 0 \ deg C. Then confirm that
Raoult's and Henry's laws are obeyed in the appropriate regions. Deduce the activities and activity
coefficients of the components on the Raoult's law basis and then, taking B as the solute, its activity and
activity coefficient on a Henry's law basis. Finally, evaluate the excess Gibbs energy of the mixture over
the composition range spanned by the data. 0 . 0 16 0 0.0439XE
0.08350.11380.17140.4840.9671.5351.892.45 Pi / kPa Pg / kPa
35.05 34.2933.2832.6430.900.36960.58340.29730.66040.84370.99
Xx3.834.845.363.316.767.29 Pp / kPa Pg / kPa
26.0820.4228.1618.0110.00.47
Transcribed Image Text:15. 2 Plot the vapour pressure data for a mixture of benzene (B) and ethanoic acid (E) given below and plot the vapour pressure / composition curve for the mixture at 5 0 \ deg C. Then confirm that Raoult's and Henry's laws are obeyed in the appropriate regions. Deduce the activities and activity coefficients of the components on the Raoult's law basis and then, taking B as the solute, its activity and activity coefficient on a Henry's law basis. Finally, evaluate the excess Gibbs energy of the mixture over the composition range spanned by the data. 0 . 0 16 0 0.0439XE 0.08350.11380.17140.4840.9671.5351.892.45 Pi / kPa Pg / kPa 35.05 34.2933.2832.6430.900.36960.58340.29730.66040.84370.99 Xx3.834.845.363.316.767.29 Pp / kPa Pg / kPa 26.0820.4228.1618.0110.00.47
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