14.27 The following are mass spectra for the constitutional isomers ethylcyclohexane and 1,1-dimethylcyclohexane. Based on likely fragmentation patterns, match each compound with its spectrum. 100 Relative Intensity Relative Intensity 80- 60- 40- 20- 0 100- 80 60 40 10 20 30 20- 0 10 20 30 40 50 60 70 80 90 m/z 40 50 60 m/z 100 110 120 70 80 90 m-29 100 110

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Can someone explain how to go about differentiating? They both have a M-29, so Im confused or maybe not analyzing it correctly. The book explained, but it was hard to understand. I took orgo last year so it's a little fuzzy, and mass spectometry is a totally new concept to me. 

14.27 The following are mass spectra for the constitutional isomers
ethylcyclohexane and 1,1-dimethylcyclohexane. Based on likely
fragmentation patterns, match each compound with its spectrum.
100
Relative Intensity
Relative Intensity
80
60-
40
20
0
100
80
60
10
40-
20-
0-
10
20
20
30
40 50 60 70
m/z
30 40 50
60
m/z
M-27
80 90
100 110 120
70 80 90
m-29
100 110
Transcribed Image Text:14.27 The following are mass spectra for the constitutional isomers ethylcyclohexane and 1,1-dimethylcyclohexane. Based on likely fragmentation patterns, match each compound with its spectrum. 100 Relative Intensity Relative Intensity 80 60- 40 20 0 100 80 60 10 40- 20- 0- 10 20 20 30 40 50 60 70 m/z 30 40 50 60 m/z M-27 80 90 100 110 120 70 80 90 m-29 100 110
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