13–12. Given that R, = 156.0 pm and k = 250.0 N-m- for 'Li"F, use the rigid rotator-harmonic ocillator approximation to construct to scale an energy-level diagram for the first five rotational levels in the v = 0 and v = 1 vibrational states. Indicate the allowed transitions in an absorption experiment, and calculate the frequencies of the first few lines in the R and P branches of the vibration-rotation spectrum of “Li®F. %3D
13–12. Given that R, = 156.0 pm and k = 250.0 N-m- for 'Li"F, use the rigid rotator-harmonic ocillator approximation to construct to scale an energy-level diagram for the first five rotational levels in the v = 0 and v = 1 vibrational states. Indicate the allowed transitions in an absorption experiment, and calculate the frequencies of the first few lines in the R and P branches of the vibration-rotation spectrum of “Li®F. %3D
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:13–12. Given that R, = 156.0 pm and k = 250.0 N-m-' for "L¡®F, use the rigid rotator-harmonic
oscillator approximation to construct to scale an energy-level diagram for the first five rotational
levels in the v = 0 and v = 1 vibrational states. Indicate the allowed transitions in an absorption
experiment, and calculate the frequencies of the first few lines in the R and P branches of the
vibration-rotation spectrum of “LI®F.
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