(c) Rotation+Vibration, continued: Choose one transition from each of the (R) and (P) branches in the table anduse the relation AE (cm-¹) = 2 B₁ (21"+1) to calculate the rotational constant for the v=1 state, B₁ Youranswer should be in cm¹. Prove, in one mathematical equation, why B₁ < Bo. 7) The Pure Rotational spectrum of isotopically pure "C="0 at room temperature isshown at right. The x-axis numbers identify the values for J" for each transition.a) If Bo= 5.763573 100 s¹, and T - 115.4 °C, for which J value will you see themost intense peak? Assume the Rigid Rotor model applies.b) Rotation Vibration: Transition energies for the Rovib spectrum of "C-10 are given in the table.Draw arrows onto the chart below and label with the letters from the table that show all the transitions.v' =1V" =0JRJ")(cm¹)0 2147.0831 (a)1 2150.8579 (b)2 2154.5975 (c)3 2158.3016 (d)P(J") (cm)-2139.4281 (e)2135.5482 (f)2131.6336 (g)

The main aim of this question is to calculate the rotational constant for the v=1 state (B₁) using…

(c) Rotation+Vibration, continued: Choose one transition from each of the (R) and (P) branches in the table and use the relation AE (cm-¹) = 2 B₁ (21"+1) to calculate the rotational constant for the v=1 state, B₁ Your answer should be in cm2. Prove, in one mathematical equation, why B₁ < Bo.

(c) Rotation+Vibration, continued: Choose one transition from each of the (R) and (P) branches in the table and use the relation AE (cm-¹) = 2 B₁ (21"+1) to calculate the rotational constant for the v=1 state, B₁ Your answer should be in cm2. Prove, in one mathematical equation, why B₁ < Bo.

Chemistry

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ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

(c) Rotation+Vibration, continued: Choose one transition from each of the (R) and (P) branches in the table and
use the relation AE (cm-¹) = 2 B₁ (21"+1) to calculate the rotational constant for the v=1 state, B₁ Your
answer should be in cm¹. Prove, in one mathematical equation, why B₁ < Bo.

7) The Pure Rotational spectrum of isotopically pure "C="0 at room temperature is
shown at right. The x-axis numbers identify the values for J" for each transition.
a) If Bo= 5.763573 100 s¹, and T - 115.4 °C, for which J value will you see the
most intense peak? Assume the Rigid Rotor model applies.
b) Rotation Vibration: Transition energies for the Rovib spectrum of "C-10 are given in the table.
Draw arrows onto the chart below and label with the letters from the table that show all the transitions.
v' =1
V" =0
JRJ")(cm¹)
0 2147.0831 (a)
1 2150.8579 (b)
2 2154.5975 (c)
3 2158.3016 (d)
P(J") (cm)
-
2139.4281 (e)
2135.5482 (f)
2131.6336 (g)

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