13.47 The solubility product for AgI in water at 25°C is 8.2 ×10-17. Use data in Table 13.1 to find E° for the Ag-AgI elec-trode at 25°C. TABLE 13.1Standard Electrode Potentials in H,0 at 25°C and 1 barHalf-cell reactionE/VHalf-cell reactionE/V2D* + 2e- → D,2H* + 2e → H,AgBr(c) + e -→ Ag + BrAGCI(c) + e → Ag + ClHg,Cl,(c) + 2e- → 2Hg(/) + 2CI¯Cu2+ + 2e -→ CuCut + e → CuL(c) + 2e → 21-Hg,SO,(c) + 2e → 2Hg(/) + SO}-Fe+ +e Fe²+Ag* + e → AgBr,() + 2e → 2Br"0,(g) + 4H* + 4e → 2H,OCl,(g) + 2e- → 2CI-Aut + e -→ AuK+ + e → K-2.936-0.01Ca?+ + 2e → CaNa+ + e → NaMg2+ + 2e → MgAl+ + 3e - Al2H,0 + 2e → H(g) + 20H¯Zn?+ + 2e -→ ZnGa+ + 3e -→ GaFe2+ + 2e FeCd2+ + 2e - CdPbl,(c) + 2e – Pb + 21-PBSO,(c) + 2e → Pb + SO;-Sn2+ + 2e → Sn(white)Pb2+ + 2e → PbFe+ + 3e-2.868-2.7140.073-2.3600.2222-1.6770.2680-0.8280.339-0.7620.518-0.5490.535-0.440.615-0.4020.771-0.365-0.3560.79921.078-0.1411.229-0.1261.360- Fe-0.041.69

Given that, Ksp of AgI in water = 8.2×10-17 E°cell for Ag+/Ag = -0.7992 V Number of electron…

Answered: 13.47 The solubility product for AgI in…

13.47 The solubility product for AgI in water at 25°C is 8.2 × 10-17. Use data in Table 13.1 to find E° for the Ag-AgI elec- trode at 25°C.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

100%

13.47 The solubility product for AgI in water at 25°C is 8.2 ×
10-17. Use data in Table 13.1 to find E° for the Ag-AgI elec-
trode at 25°C.

TABLE 13.1
Standard Electrode Potentials in H,0 at 25°C and 1 bar
Half-cell reaction
E/V
Half-cell reaction
E/V
2D* + 2e- → D,
2H* + 2e → H,
AgBr(c) + e -→ Ag + Br
AGCI(c) + e → Ag + Cl
Hg,Cl,(c) + 2e- → 2Hg(/) + 2CI¯
Cu2+ + 2e -→ Cu
Cut + e → Cu
L(c) + 2e → 21-
Hg,SO,(c) + 2e → 2Hg(/) + SO}-
Fe+ +e Fe²+
Ag* + e → Ag
Br,() + 2e → 2Br"
0,(g) + 4H* + 4e → 2H,O
Cl,(g) + 2e- → 2CI-
Aut + e -→ Au
K+ + e → K
-2.936
-0.01
Ca?+ + 2e → Ca
Na+ + e → Na
Mg2+ + 2e → Mg
Al+ + 3e - Al
2H,0 + 2e → H(g) + 20H¯
Zn?+ + 2e -→ Zn
Ga+ + 3e -→ Ga
Fe2+ + 2e Fe
Cd2+ + 2e - Cd
Pbl,(c) + 2e – Pb + 21-
PBSO,(c) + 2e → Pb + SO;-
Sn2+ + 2e → Sn(white)
Pb2+ + 2e → Pb
Fe+ + 3e
-2.868
-2.714
0.073
-2.360
0.2222
-1.677
0.2680
-0.828
0.339
-0.762
0.518
-0.549
0.535
-0.44
0.615
-0.402
0.771
-0.365
-0.356
0.7992
1.078
-0.141
1.229
-0.126
1.360
- Fe
-0.04
1.69

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