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13. Given the following interactions, what is the difference in the amount of strain associated with the conformations show Me/Me gauche: 0.9 kcal/mol Me/H 1,3-diaxial: 0.9 kcal/mol OH/H 1,3-diaxial: 0.25 kcal/mol (A) 0.4 kcal/mol (B) 0.9 kcal/mol OH Me -Me Me ring inversion HO Me (C) 1.3 kcal/mol (D) 1.8 kcal/mol Me Me if th EU an

13. Given the following interactions, what is the difference in the amount of strain associated with the conformations show Me/Me gauche: 0.9 kcal/mol Me/H 1,3-diaxial: 0.9 kcal/mol OH/H 1,3-diaxial: 0.25 kcal/mol (A) 0.4 kcal/mol (B) 0.9 kcal/mol OH Me -Me Me ring inversion HO Me (C) 1.3 kcal/mol (D) 1.8 kcal/mol Me Me if th EU an

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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13. Given the following interactions, what is the difference in the amount of strain associated with the conformations show Me/Me gauche: 0.9 kcal/mol Me/H 1,3-diaxial: 0.9 kcal/mol OH/H 1,3-diaxial: 0.25 kcal/mol F CI OH -F (B) CI Me -Me Me (A) 0.4 kcal/mol (B) 0.9 kcal/mol (C) 1.3 kcal/mol (D) 1.8 kcal/mol 14. Which structure represents the most stable conformation of trans-1-chloro-3-fluorocyclohexane if the F/H and interactions are 0.12 and 0.25 kcal/mol, respectively? CI ring inversion A F (A) (C) 15. Which compound is chiral and can exist as a pair of enantiomers? (A) cis-1,3-dimethylcyclobutane (B) trans-1,3-dimethylcyclobutane (C) cis-1,2-dimethylcyclobutane (D) trans-1,2-dimethylcyclobutane HO Me Me (D) Me
Transcribed Image Text:13. Given the following interactions, what is the difference in the amount of strain associated with the conformations show Me/Me gauche: 0.9 kcal/mol Me/H 1,3-diaxial: 0.9 kcal/mol OH/H 1,3-diaxial: 0.25 kcal/mol F CI OH -F (B) CI Me -Me Me (A) 0.4 kcal/mol (B) 0.9 kcal/mol (C) 1.3 kcal/mol (D) 1.8 kcal/mol 14. Which structure represents the most stable conformation of trans-1-chloro-3-fluorocyclohexane if the F/H and interactions are 0.12 and 0.25 kcal/mol, respectively? CI ring inversion A F (A) (C) 15. Which compound is chiral and can exist as a pair of enantiomers? (A) cis-1,3-dimethylcyclobutane (B) trans-1,3-dimethylcyclobutane (C) cis-1,2-dimethylcyclobutane (D) trans-1,2-dimethylcyclobutane HO Me Me (D) Me
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