12. List the reagents that generate a carbocation intermediate. Reagents sheet provided on exam. Some changes to the reagent sheet may occur. NANH2 (or NaH) NaNH2 (excess) 1. NaNHz (3 eq) 2. H-О H2, Pt (or Pd) H2, Lindlar Na, NH3 H9SO4, H2SO4, H;O 1. R,BH (like (sia),BH or 9-BBN) 2. H2O2, NaOH HBr (1 eq) NaOMe KОBu or KOC(CH)з 1. TsCl, pyridine 2. nucleophile HBr H2SO4 (concentrated, sometimes shown with heat or A) H2, Pt (or Pd) X2 like Br2 Br2, H2O H2SO4, H2O (or "dilute sulfuric acid," or H3O*, or H*, H2O) HBr (excess, or 2 eq) Br2 (1 eq) Br2 (excess, or 2 eq) Br2, hv HBr, ROOR HBr 1. Hg(ОАc);, НH-0 2. NaBHa 1. ВН, 1. O3 1. OsO4 2. NaHSO3, H2O mcpba (or RCO;H) 2. H2O2, NaOH 2. DMS ((CH:)2S) (or Zn/H2O)

12. List the reagents that generate a carbocation intermediate. Reagents sheet provided on exam. Some changes to the reagent sheet may occur. NANH2 (or NaH) NaNH2 (excess) 1. NaNHz (3 eq) 2. H-О H2, Pt (or Pd) H2, Lindlar Na, NH3 H9SO4, H2SO4, H;O 1. R,BH (like (sia),BH or 9-BBN) 2. H2O2, NaOH HBr (1 eq) NaOMe KОBu or KOC(CH)з 1. TsCl, pyridine 2. nucleophile HBr H2SO4 (concentrated, sometimes shown with heat or A) H2, Pt (or Pd) X2 like Br2 Br2, H2O H2SO4, H2O (or "dilute sulfuric acid," or H3O, or H, H2O) HBr (excess, or 2 eq) Br2 (1 eq) Br2 (excess, or 2 eq) Br2, hv HBr, ROOR HBr 1. Hg(ОАc);, НH-0 2. NaBHa 1. ВН, 1. O3 1. OsO4 2. NaHSO3, H2O mcpba (or RCO;H) 2. H2O2, NaOH 2. DMS ((CH:)2S) (or Zn/H2O)

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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