111O Organic Acids and BasesUnderstanding the influence of induction on site acidityRank the following organic molecules in order of decreasing acidity.That is, select '1' in the second column for the most acidic molecule, '2' for the next most acidic molecule, and so on.HOHOHOOCICICI(Choose one)CI(Choose one)OCICI(Choose one)ད་ལ།ཡིག་སྦུད་ExplanationCheck(Choose one)OHXG

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Answered: 111 O Organic Acids and Bases…

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter20: Carboxylic Acids And Nitriles

Section20.4: Substituent Effects On Acidity

Problem 9P

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Rank the following organic molecules in order of decreasing acidity. That is, select '1' in the second column for the most acidic molecule, '2' for the next most acidic molecule, and so on. HO HO Jl. CI OH OH (Choose one) (Choose one) (Choose one) ▼ (Choose one) ▼ X
1a) Consider the reaction AH(+) + H₂O A: + H3O+). For the following named acids: a) draw the structure of the acid, b) give the approximate pKa of the conjugate acid in units of 5, c) give the name of the conjugate base, and d) draw the structure of the conjugate base. p-Toluenesulfonic acid acid Conjugate base Imidazolium cation pka_ pKa iso-Propanol pKa Acetylene pKa
Can any functional groups on Risperidone ionize? If so, which ones? Under what conditions? What are the pKa values of these functional groups? Write the structures in their correct ionization state at physiological pH.
The most acidic proton on the molecule below has pKa 41. Which of the following bases are capable of deprotonating the proton? Check all that apply.
What do you mean by carbon acid? What is the range of their pKa's?
The structure of a particular drug is provided below. The acid form is shown, and its pk, is 4.8. Mark any/all that apply. HO O The conjugate base of this acid is charged. O The acid form will predominate at pH 7.40. The acid form of this drug is charged. The conjugate base will predominate at pH 7.40. The acid form of this drug will diffuse through the cell membrane more easily than the conjugate base will diffuse through the cell membrane.
Using pKa Values to Determine Relative Acidity and Basicity Rank the following compounds in order of increasing acidity, and then rank their conjugate bases in order of increasing basicity.
1) Consider the reaction AH+ H₂O A:+H3O¹. For the following named acids: 1) draw the structure of the acid, 2) give the approximate pKa value of the acid in multiples of 5, 3) give the name of the conjugate base, and 4) draw the structure of the conjugate base. m-Chlorophenol 3-Pentanone acid Conj. base acid Conj. base pKa Benzoic acid pka_ iso-Butyl ammonium ion pka_ Diethyl Malonate pka_ Benzyl oxonium ion pka_ 1-pentyne pKa pKa Ethyl Acetate pKa
Conjugate base acid 1a. Consider the reaction AH(+) + H₂O →> A:(-) + H3O+). For the following named acids: a) draw the structure of the acid, b) give the approximate pKa of the conjugate acid in units of 5, c) give the name of the conjugate base, and d) draw the structure of the conjugate base. Dimethyl sulfoxide pKa Acrylic Acid pKa Ethyl Acetate pKa Benzamide pKa
How did you know the molecules were weak or strong acid? Please give the pKa if that's the method you used. Please explain in detail.
4 5 Arrange the following bases in increasing base strength. There is no partial credit on this problem. Weakest base 1 2 3 Pyridine (C5H5N), Kb = 1.7 x 10-⁹ Aniline (C6H5NH2), Kb = 3.9 x 10-10 Strongest base Methylamine (CH3NH₂), Kb = 4.4 x 10-4 Hydrazine (N2H4), Kb = 1.3 x 10-6 ⠀ Dimethylamine ((CH3)2NH), K₂ = 5.1 x 10-4

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