11) The 'H NMR spectrum of an unknown compound shows a sharp singlet at 9.8 ppm. Which of the following would produce a 'H NMR spectrum that would also feature a singlet in this location? HO. d) a) H. b) ОН С)

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Chapter1: Chemical Foundations
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**Question 11**: The \( \text{H}^1 \) NMR spectrum of an unknown compound shows a sharp singlet at 9.8 ppm. Which of the following would produce a \( \text{H}^1 \) NMR spectrum that would also feature a singlet in this location?

**Options:**

a) ![Image of compound a](image-url)  
(A structure featuring a benzene ring with an aldehyde group attached.)

b) ![Image of compound b](image-url)  
(A structure similar to option a, but with an additional hydroxyl group.)

c) ![Image of compound c](image-url)  
(A structure featuring a benzene ring with an alcohol group attached at the end of the chain.)

d) ![Image of compound d](image-url)  
(A structure featuring a benzene ring with a triple bond at the end of the chain, characteristic of a phenylacetylene compound.)

**Explanation**: Each of these chemical structures is illustrated with functional groups that can affect the NMR spectrum. The singlet at 9.8 ppm typically indicates the presence of an aldehyde proton, so the correct answer is the structure that includes an aldehyde group connected to a benzene ring (option a).
Transcribed Image Text:**Question 11**: The \( \text{H}^1 \) NMR spectrum of an unknown compound shows a sharp singlet at 9.8 ppm. Which of the following would produce a \( \text{H}^1 \) NMR spectrum that would also feature a singlet in this location? **Options:** a) ![Image of compound a](image-url) (A structure featuring a benzene ring with an aldehyde group attached.) b) ![Image of compound b](image-url) (A structure similar to option a, but with an additional hydroxyl group.) c) ![Image of compound c](image-url) (A structure featuring a benzene ring with an alcohol group attached at the end of the chain.) d) ![Image of compound d](image-url) (A structure featuring a benzene ring with a triple bond at the end of the chain, characteristic of a phenylacetylene compound.) **Explanation**: Each of these chemical structures is illustrated with functional groups that can affect the NMR spectrum. The singlet at 9.8 ppm typically indicates the presence of an aldehyde proton, so the correct answer is the structure that includes an aldehyde group connected to a benzene ring (option a).
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