10.16 Design a preparation of each of the following compounds from an alcohol using sulfonate ester methodology. (a) (b) -CH,CH,CH,- SCH,

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10.16 Design a preparation of each of the following compounds from an alcohol using sulfonate ester methodology.
(a)
(b)
-CH,CH,CH,– SCH,
10.21 (a) According to the mechanism of the reaction shown in Eq. 10.34, what would be the absolute configuration of the alkyl
chloride obtained from the reaction of thionyl chloride with (S)-CH,CH,CH,CHD-OH? Explain.
(b) According to the mechanism shown in Eqs, 10,36a and 10.36b, what would be the absolute configuration of
2-bromopentane obtained from the reaction of Ph,PBr, with the R enantiomer of 2-pentanol? Explain.
Transcribed Image Text:10.16 Design a preparation of each of the following compounds from an alcohol using sulfonate ester methodology. (a) (b) -CH,CH,CH,– SCH, 10.21 (a) According to the mechanism of the reaction shown in Eq. 10.34, what would be the absolute configuration of the alkyl chloride obtained from the reaction of thionyl chloride with (S)-CH,CH,CH,CHD-OH? Explain. (b) According to the mechanism shown in Eqs, 10,36a and 10.36b, what would be the absolute configuration of 2-bromopentane obtained from the reaction of Ph,PBr, with the R enantiomer of 2-pentanol? Explain.
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