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6.) Synthesize the following molecules from benzene or toluene, and any alkyl halide if needed. Provide retrosynthetic analysis:

6.) Synthesize the following molecules from benzene or toluene, and any alkyl halide if needed. Provide retrosynthetic analysis:

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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**Problem 6: Synthesis Challenge** **Objective:** Synthesize the following molecules using benzene or toluene, with any necessary alkyl halide. Provide a detailed retrosynthetic analysis. **Molecules to Synthesize:** - **a)** A biphenyl compound with a nitro group attached to one benzene ring. The structure shows a nitro group (NO₂) para to the biphenyl linkage. - **b)** A substituted cyclohexylbenzene with a nitro group and a sulfonic acid group. The nitro group (NO₂) is para to the sulfonic acid group (SO₃H) on the benzene ring, and the cyclohexyl group is directly attached to the benzene ring. For both molecules, identify starting materials and devise a synthetic route, considering the constraints of starting with benzene or toluene and potentially using alkyl halides. Reverse-engineer the target molecules to assist in planning the forward synthesis.
Transcribed Image Text:**Problem 6: Synthesis Challenge** **Objective:** Synthesize the following molecules using benzene or toluene, with any necessary alkyl halide. Provide a detailed retrosynthetic analysis. **Molecules to Synthesize:** - **a)** A biphenyl compound with a nitro group attached to one benzene ring. The structure shows a nitro group (NO₂) para to the biphenyl linkage. - **b)** A substituted cyclohexylbenzene with a nitro group and a sulfonic acid group. The nitro group (NO₂) is para to the sulfonic acid group (SO₃H) on the benzene ring, and the cyclohexyl group is directly attached to the benzene ring. For both molecules, identify starting materials and devise a synthetic route, considering the constraints of starting with benzene or toluene and potentially using alkyl halides. Reverse-engineer the target molecules to assist in planning the forward synthesis.
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