10. Water gas, a commercial fuel, is made by the reaction of hot coke carbon with steam: C(s)+H2O(g) CO(g) + H2(g) When equilibrium is established at 832°C, the concentrations of CO, H₂, and H₂O are 4.00 × 102, 4.00 × 102, and 1.00 x 10-2 mol/L, respectively. Calculate the value of AG° for this reaction at 832°C. (10 points) 11. The reaction 4Ag(s) + O2(g) →2Ag2O(s), AH°=-61.14 kJ and AS° =-132 J/K is spontaneous at 25°C. At what temperature will the reaction no longer be spontaneous? Assume that AH° and AS° are essentially temperature independent. (8 points)

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10. Water gas, a commercial fuel, is made by the reaction of hot coke carbon with steam:
C(s)+H2O(g) CO(g) + H2(g)
When equilibrium is established at 832°C, the concentrations of CO, H₂, and H₂O are 4.00 × 102,
4.00 × 102, and 1.00 x 10-2 mol/L, respectively. Calculate the value of AG° for this reaction at 832°C.
(10 points)
11. The reaction 4Ag(s) + O2(g) →2Ag2O(s), AH°=-61.14 kJ and AS° =-132 J/K is spontaneous at
25°C. At what temperature will the reaction no longer be spontaneous? Assume that AH° and AS° are
essentially temperature independent. (8 points)
Transcribed Image Text:10. Water gas, a commercial fuel, is made by the reaction of hot coke carbon with steam: C(s)+H2O(g) CO(g) + H2(g) When equilibrium is established at 832°C, the concentrations of CO, H₂, and H₂O are 4.00 × 102, 4.00 × 102, and 1.00 x 10-2 mol/L, respectively. Calculate the value of AG° for this reaction at 832°C. (10 points) 11. The reaction 4Ag(s) + O2(g) →2Ag2O(s), AH°=-61.14 kJ and AS° =-132 J/K is spontaneous at 25°C. At what temperature will the reaction no longer be spontaneous? Assume that AH° and AS° are essentially temperature independent. (8 points)
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