10. For each set of reactions, 1) identify the reaction mechanism as SN1, Sn2, E1, and/or E2 (write in box at left), 2) fill in the missing reactants, reagents, or major product(s), and 3) provide a curved-arrow mechanism. Make sure to include relevant stereochemistry.
10. For each set of reactions, 1) identify the reaction mechanism as SN1, Sn2, E1, and/or E2 (write in box at left), 2) fill in the missing reactants, reagents, or major product(s), and 3) provide a curved-arrow mechanism. Make sure to include relevant stereochemistry.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Transcription and Explanation for Educational Use:**
---
**Instructions:**
10. For each set of reactions, 1) identify the reaction mechanism as \( S_N1 \), \( S_N2 \), E1, and/or E2 (write in box at left), 2) fill in the missing reactants, reagents, or major product(s), and 3) provide a curved-arrow mechanism. Make sure to include relevant stereochemistry.
---
### Reaction Set 1:
**Reactant:**
- A benzyl bromide compound with a double bond in the alkene group.
**Reagents:**
- Sodium chloride (NaCl) in the presence of water (\( H_2O \)).
**Mechanism Type:**
- A box to determine whether it's \( S_N1 \), \( S_N2 \), E1, or E2.
**Requirements:**
- Determine the product and provide the mechanism with sterochemistry.
---
### Reaction Set 2:
**Reactant:**
- A tert-butoxide ion in dichloromethane (\( CH_2Cl_2 \)).
**Product:**
- An alkene with two methyl groups on the first carbon.
**Mechanism Type:**
- A box to decide if it's \( S_N1 \), \( S_N2 \), E1, or E2.
**Requirements:**
- Identify missing reactants/reagents and demonstrate the mechanism.
---
### Reaction Set 3:
**Reactant:**
- A cyclopentyl chloride with an explicit stereochemistry showing wedge bonds.
**Reagents:**
- Sodium cyanide (\( NaCN \)) in dimethylformamide (DMF).
**Mechanism Type:**
- A box to specify \( S_N1 \), \( S_N2 \), E1, or E2.
**Requirements:**
- Predict product and explain with a curved-arrow mechanism considering stereochemistry.
---
### Reaction Set 4:
**Reactant:**
- Cyclohexanol with an attached OH group.
**Reagents:**
- \( H^+ / H_2O \) with heat.
**Mechanism Type:**
- A box to label as \( S_N1 \), \( S_N2 \), E1, or E2.
**Requirements:**
- Determine the resulting product and describe the reaction mechanism.
---
### Reaction Set 5:
**Reactant:**
- A chlor
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