10. For each of the following pairs of metal complexes, circle the one that will most readily do an oxidative addition to the substrate shown. No discussion is necessary. A. CH3I: RhCI(CO)3 - or - IrH(CO)(PMe3)2 B. CH3I: Rh(I)(CO) {P(tert-butyl)3}2 - or - [Re(CO)3(dmpe)]¯¯ C. H2: Cp2Nb(NMe)(CH3) - or - [Rh(CO)212] D. Cl2: Mo(CO)3 {P(OMe)3}3 - or - Mo(CO)3(PMe3)3
10. For each of the following pairs of metal complexes, circle the one that will most readily do an oxidative addition to the substrate shown. No discussion is necessary. A. CH3I: RhCI(CO)3 - or - IrH(CO)(PMe3)2 B. CH3I: Rh(I)(CO) {P(tert-butyl)3}2 - or - [Re(CO)3(dmpe)]¯¯ C. H2: Cp2Nb(NMe)(CH3) - or - [Rh(CO)212] D. Cl2: Mo(CO)3 {P(OMe)3}3 - or - Mo(CO)3(PMe3)3
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter24: Catalytic Carbon-carbon Bond Formation
Section: Chapter Questions
Problem 24.22P
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![10. For each of the following pairs of metal complexes, circle the one that will most readily do an
oxidative addition to the substrate shown. No discussion is necessary.
A. CH3I: RhCl(CO)3 - or - IrH(CO)(PMe3)2
B. CH3I: Rh(I)(CO) {P(tert-butyl)3}2- or - [Re(CO)3(dmpe)]¯¯
C. H2: Cp2Nb(NMe)(CH3) - or - [Rh(CO)2]2]¯
D. Cl2: Mo(CO)3 {P(OMe)3}3 - or - Mo(CO)3(PMe3)3](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F878ef908-c816-4097-919e-37ca4cdfda42%2F22c6a713-5a6b-48e6-8065-da302776a258%2F16t4jvj_processed.jpeg&w=3840&q=75)
Transcribed Image Text:10. For each of the following pairs of metal complexes, circle the one that will most readily do an
oxidative addition to the substrate shown. No discussion is necessary.
A. CH3I: RhCl(CO)3 - or - IrH(CO)(PMe3)2
B. CH3I: Rh(I)(CO) {P(tert-butyl)3}2- or - [Re(CO)3(dmpe)]¯¯
C. H2: Cp2Nb(NMe)(CH3) - or - [Rh(CO)2]2]¯
D. Cl2: Mo(CO)3 {P(OMe)3}3 - or - Mo(CO)3(PMe3)3
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