10. An expression for the rate of the reaction is; A) Rate = K (CH,Br [OH) B) Rate = K [CH,Br [OH] C) Rate = K [CH,Br] [OH] D) Rate = K [CH, Brl [OH]

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Chapter1: Chemical Foundations
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Answer Q10, 11, 12

What is the overal order of the reaction?
11.
A) 0
C) 3
In a study of the rate of reaction
X(aq) + Y(aq) > Z(aq), solution
containing different initial concentrations of
X and Y were allowed to react. The time taken
for concentration of Z to reach a certain level
was measured. The results are shown below
7.
B) 1
D) 2
The graph below shows the variation of enerov
against reaction path for an exathermic reaction
Time
Initial [X]
moll
Initial [Y]
moll
Energy
taken s
0.1
0.1
161
0.1
0.2
80
Reactant
54
0.1
0.2
0.3
0.1
39
0.3
0.1
18
Podut
The right expression for the rate of reaction in
terms of concentration of X and Y ia
A) Rate = K[X][Y]
B) Rate = K[X] [YP
C) Rate = K [XF M
D) Rate = K (X] IYP
Reaction path
12. Which of the letters A to C represents the
activation energy for the reaction?
Questions 13 and 14
Z, the rate is
For the reaction X + 2Y
quadrupled when (X] is doubled and [Y] is kept
constant. It is doubled when [Y] is doubled and
[XI in kept constant.
Questions a and 9
The preparation of ethylbromide from
elhanol is thought to proceed by the
following mechanism
8.
13. The right rate expression for the reaction is
A) Rate = K[Y]X
B) Rate = K [YP [X]
C) Rate = K[YTIXI
D) Rate = K[XTY
) CH CH-OH-
H'
Fast
>CH,CH,-OH step I
ii) CH,-CH-OH +Br S CH,-CH-OH step I
i) CH,-CH,-OH: CH,CH,Br +H,O; step II
14. What will be the effect on the rate of the
reaction when [X] is halved while [Y] in kept
constant?
Br
Which step(s) is the rate determining step?
A) Steps I and II
C) Steps II and II
A) Rate of reaction is halved
B) Rate of reaction is multiplied by a quarter
C) Rate of reaction is squared
D) Rate of reaction is quadrupled.
B) Steps Il only
D) Step I only
9.
State the order of the reaction
A) 2
C) 0
B) 1
D) none of the above.
15. The table below gives some data concerning
a reaction belween two compounds A and B.
Questions 10 and 11
Concentration of
Rate of
The rate of the reaction
A and B (moldm)
Reaction
CH Br + OH
directly proportional to the concentration of
bromo methane and hydroxyl ln.
-> CH OH + Br is
B
12
15
36
10
24
10. An expression for the rate of the reaction is;
A) Rate = K (CH, Br (OH]
B) Rate = K [CH Br]" [OH]
C) Rate = K [CH,Br [OH)
D) Rate = K [CH Br [OH]
The partial order of the reaction with respect to
compound A is
A) 3
C) 2
B) 1
D) 0
160
Transcribed Image Text:What is the overal order of the reaction? 11. A) 0 C) 3 In a study of the rate of reaction X(aq) + Y(aq) > Z(aq), solution containing different initial concentrations of X and Y were allowed to react. The time taken for concentration of Z to reach a certain level was measured. The results are shown below 7. B) 1 D) 2 The graph below shows the variation of enerov against reaction path for an exathermic reaction Time Initial [X] moll Initial [Y] moll Energy taken s 0.1 0.1 161 0.1 0.2 80 Reactant 54 0.1 0.2 0.3 0.1 39 0.3 0.1 18 Podut The right expression for the rate of reaction in terms of concentration of X and Y ia A) Rate = K[X][Y] B) Rate = K[X] [YP C) Rate = K [XF M D) Rate = K (X] IYP Reaction path 12. Which of the letters A to C represents the activation energy for the reaction? Questions 13 and 14 Z, the rate is For the reaction X + 2Y quadrupled when (X] is doubled and [Y] is kept constant. It is doubled when [Y] is doubled and [XI in kept constant. Questions a and 9 The preparation of ethylbromide from elhanol is thought to proceed by the following mechanism 8. 13. The right rate expression for the reaction is A) Rate = K[Y]X B) Rate = K [YP [X] C) Rate = K[YTIXI D) Rate = K[XTY ) CH CH-OH- H' Fast >CH,CH,-OH step I ii) CH,-CH-OH +Br S CH,-CH-OH step I i) CH,-CH,-OH: CH,CH,Br +H,O; step II 14. What will be the effect on the rate of the reaction when [X] is halved while [Y] in kept constant? Br Which step(s) is the rate determining step? A) Steps I and II C) Steps II and II A) Rate of reaction is halved B) Rate of reaction is multiplied by a quarter C) Rate of reaction is squared D) Rate of reaction is quadrupled. B) Steps Il only D) Step I only 9. State the order of the reaction A) 2 C) 0 B) 1 D) none of the above. 15. The table below gives some data concerning a reaction belween two compounds A and B. Questions 10 and 11 Concentration of Rate of The rate of the reaction A and B (moldm) Reaction CH Br + OH directly proportional to the concentration of bromo methane and hydroxyl ln. -> CH OH + Br is B 12 15 36 10 24 10. An expression for the rate of the reaction is; A) Rate = K (CH, Br (OH] B) Rate = K [CH Br]" [OH] C) Rate = K [CH,Br [OH) D) Rate = K [CH Br [OH] The partial order of the reaction with respect to compound A is A) 3 C) 2 B) 1 D) 0 160
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