10. (13 pts.) Synthesize the following ether from propane, cyclohexane, methyl iodide, and any oxidants, inorganic reagents and bases. Do not draw mechanism. + CH3I OCH3
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- (14) Mechanism :0 Ö NaOH 1 -0²³What reagent(s) are suitable to carry out the conversion shown? OH an OA. 1.03; 2.1 equivalent of NaBH4/CH3OH OB.1. 03. 2. (CH3)2S: 3. H3O* OC.1.03; 2. (CH3)2S; 3. excess NaBH4/CH3OH A and B OB and C OH8. (20 pt) Draw a mechanism for step 1 and a product & mech with a 2nd equiv. of MeMgBr. Me-MgBr MeMgBr ? MeO H Me HCI workup
- 11. (12 pts) Provide a complete mechanism for the reaction, including all lone pairs, formal charges, and curved arrows. H₂O Хон4:31 PM Mon May 8 ← Problem 22 of 30 1) PhMgCl (C6H5MgCl) 2) HCI/H₂O Draw the products resulting from addition of a Grignard reagent to an aldehyde. Use a dash or wedge bond to indicate stereochemistry of substituents on asymmetric centers, Ignore any inorganic byproducts. CI @ 90% H SubmitDraw the major organic product for the reaction. (Include mechanism)
- 7.Which reagent(s) best complete the following reaction? 1. NaBH4 2. NaOH Cu(CH,CH,CH,CH;), (2 eq) 3. BrCH,CH,C,CH; (2 cq) II 1. Li CH,CH,CH,CH; (2 eq) 2. 1;0* 1. BrMg CH;CH,CH,CH; (2 eq) 2. 1;0" III IV a. d. IV Both II and IV will complete the reaction. e. с. II REF: 20.8Which set of reagents would be appropriate to synthesize bromobenzene from benzene? O 1. HNO3 in H2SO4; 2. H2CrO4 and heat O 1. H2CrO4 and heat; 2. H2 Pd/C O Br2 and FeBr3 O 1. CH3CH2CHCI and AICI3; 2. H2CRO4 and heat O4B12 and Fe O Heat and Br2 OBR2, HCI10:29 0. O ? 86% AIATS For Two Year Medic. A 61 /180 (02:55 hr min Mark for Review When 2-Methylpropene undergoes oxidation in the presence of acidic K2Cr2O7, the products obtained are CH3 – CH + CO2 CH3 — СH — С—ОН-СО, CH, -C =0+CO2 +H2O CH3 CH; – CH2 – CH + CO2 + H20 Clear Response III
- Hi would you mind finishing question 1? I need to identify which steps show a substitution reaction for the two reactions given. Thank you!10:08 AM Thu Mar 23 ← Problem 35 of 23 Draw the major product of this reaction. Ignore inorganic byproducts. + AICI 3 > @ 66% O SubmitV. Show a synthesis of the following mostly (Z)-alkene molecule starting from benzene (C6H6), any other alkynes (R-C C-R) or alcohols (R-OH) of four (4) carbons or fewer, and any other necessary reagents and solvents that do not become part of the product. (20 pts) [reaction mechanisms are NOT required] H CH3 C=C OH -C-CH₂CH₂CH2CH2CH2CH3 H₂CH₂CH₂CH₂ CH₂O