1.3. Give possible products for the reactions of M-hydride elimination and Ferrocene reactions(a) (5-C5H5)Fe(CO)2Et(b) Ru(P3)2(Et)(CO)(c) Fe(C5H5)2 + MeCOCI / AICI 3www(d) Fe(C5H5)2 + H2C=CHR / AICI 3(e) Fe(C5H5)2 + CH₂O/HF

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Answered: 1.3. Give possible products for the…

Chemistry

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Chapter1: Chemical Foundations

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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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AgNazt Cu-Agt_Cu[(103)2 Acidic Solution
Potentially Useful Information Spectrochemical Series: | < Br < SCN < Cl° < NO3¯< F° < OH° < C2O4²- ~ H2O < NCS < NH3 < en < PPH3 A student synthesizes and isolates the following coordination compound [Ni(H2NCH2CH2NH2)3]Cl2 (molar mass = 309.8966 g/mol) according to the balanced reaction below. In the experiment, the student reacts 2.500 g of nickel (II) chloride hexahydrate (molar mass = 237.6878 g/mol) with 4.000 g of ethylenediamine (molar mass = 60.0992 g/mol). After isolating the product, the student collects 3.200 g of the nickel coordination compound. NICI2•6H2O (aq) + 3H2NCH2CH2NH2 (1) → [Ni(H2NCH2CH2NH2)3]Cl2 (s) + 6H2O (1) Given the transition metal compound, Na4[Co(C204) (CN)4], what is the oxidation state of cobalt, as well as the coordination number of cobalt in this compound? This compound is soluble in water. The oxidation state of cobalt is Cobalt has a coordination number of Your answer should be an integer.
Complete the changes in concentrations for each of the following reactions. please tell or show how to solve the problems. (b) Cu2SO4(s) 2 Cu+(aq) + SO42−(aq) Reaction Cu2SO4(s) 2 Cu+(aq) + SO42−(aq) relative change +x (c) Cr(CN)3(s) Cr3+(aq) + 3 CN−(aq) Reaction Cr(CN)3(s) Cr3+(aq) + 3 CN−(aq) relative change +x (d) Fe(CN)Br(s) Fe2+(aq) + CN−(aq) + Br−(aq) Reaction Fe(CN)Br(s) Fe2+(aq) + CN−(aq) + Br−(aq) relative change +x
You want to determine the amount of iron(III) in acomplex salt. You make a 100.0 mL solution of the complex salt by dissolving 0.0670 g of complex salt with water to the mark on a 100.0 mL volumetric flask. You get an absorbance reading for the iron from the spectrometer of 0.334. The molar absorptivity is determined to be 17605 L/mole∙cm and the pathlength is 1.00 cm. Determine the molarity of iron(III) in solution. Determine the mass percentage of iron(III) in the complex salt.
Formation constant and Gibbs free energy For the complex formation reaction where Mis any metal and L is any ligand, M+ + 2L = [ML2]* Kr is the formation constant for the complex at equilibrium and AG is the Gibbs free energy change for the reaction at equilibrium. The formation constant (K) can be related to the Gibbs free energy change (AG°) for a reaction by the equation AG° = RT In Kr where T is the temperature in kelvins and R is the gas constant equal to 8.314 J K. mol. The complex formation is generally a spontaneous process; thus, the Gibbs free energy change is negative. Part B Calculate the formation constant for the formation of [Cu(en) (H2O)4 from (Cu(H20)6]+, given that AG° is -60.1kJ - mol at 298 K.
Hh.88.
6. a) Discuss the relationship between the octahedral splitting energy, (Aoct), for complex ions and the ligand strength of the ligands in the complex ion. b) Considering only the complexes, Ni(en)3²+ (aq), Ni(NH3)²+(aq), and Ni(H₂O)62+ (aq), determine the relative ligand strengths of ammonia, ethylenediamine and water. Place the ligands in increasing order of ligand strength. (weakest ligand to the strongest ligand.) c) Discuss how you arrived at your conclusion in part b. Include in your discussion your data and/or your calculated values for these complex ions to support your conclusion.
Write the chemical equation It got cut off (K4[Fe(CN)6](aq))

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1.3. Give possible products for the reactions of M-hydride elimination and Ferrocene reactions (a) (5-C5H5)Fe(CO)2Et (b) Ru(P3)2(Et)(CO) (c) Fe(C5H5)2 + MeCOCI / AICI 3 www (d) Fe(C5H5)2 + H2C=CHR / AICI 3 (e) Fe(C5H5)2 + CH₂O/HF