Formation constant and Gibbs free energy For the complex formation reaction where Mis any metal and L is any ligand, - [ML2]+ M+ + 2L = Kr is the formation constant for the complex at equilibrium and AG is the Gibbs free energy change for the reaction at equilibrium. The formation constant (K) can be related to the Gibbs free energy change (AG°) for a reaction by the equation AG = RT In Kf where T is the temperature in kelvins and R is the gas constant equal to 8.314 J K. mol. The complex formation is generally a spontaneous process; thus, the Gibbs free energy change is negative. Part B Calculate the formation constant for the formation of [Cu(en) (H2O)4 from (Cu(H20)6]+, given that AG° is -60.1kJ - mol at 298 K

Formation constant and Gibbs free energy For the complex formation reaction where Mis any metal and L is any ligand, - [ML2]+ M+ + 2L = Kr is the formation constant for the complex at equilibrium and AG is the Gibbs free energy change for the reaction at equilibrium. The formation constant (K) can be related to the Gibbs free energy change (AG°) for a reaction by the equation AG = RT In Kf where T is the temperature in kelvins and R is the gas constant equal to 8.314 J K. mol. The complex formation is generally a spontaneous process; thus, the Gibbs free energy change is negative. Part B Calculate the formation constant for the formation of [Cu(en) (H2O)4 from (Cu(H20)6]+, given that AG° is -60.1kJ - mol at 298 K

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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