1. What conditions of temperature and pressure favor products in the following reaction: PCl5(g) ⇌ PCl3(g) + Cl2(g) ΔH = 238 kJ/mol

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1. What conditions of temperature and pressure favor products in the following reaction:

PCl5(g) ⇌ PCl3(g) + Cl2(g) ΔH = 238 kJ/mol

 

2. Consider the system below. When equilibrium is restored, how will the number of each type of molecule and the concentration of each substance compare to those before the stress was introduced? Complete the following table using the words “decrease,” “same,” or “increase.”

2 NH3(g) ⇌ N2(g) + 3 H2(g)      ΔH = 92.4 kJ/mol

 

   

Decrease Volume

Decrease Temperature


Equilibrium Concentration

N2

   

H2

   

NH3

   

Equilibrium Number

N2

   

H2

   

NH3

   



3. Nitric acid is produced commercially by the Ostwald process. The first step of the Ostwald process is:

4 NH3(g) + 5 O2(g) ⇌ 4 NO(g) + 6 H2O(g) + energy

In which direction will the above system shift in the following situations:

3. (a) Some NO is added.

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