1. The two mass spectra below correspond to two isomers of CSH10O2: methyl butanoate and valeric acid. Match the spectrum with the appropriate compound. Place the m/z ratio and the structures (show all atoms) for the labeled fragments in the table below. 100 - Compound HS-NU-1700 80 - Methyl butanoate 60 40 CH3 H3C 20 10 20 30 40 50 60 70 80 90 100 m/z 100 - Compound HS-NU-3125 3 80 Valeric acid 60 - 4 40 H3C. HO, 20 - 10 20 30 40 50 60 70 80 90 100 m/z Fragment 1 74 Fragment 2 Fragment 3 Fragment 4 87 m/z Fragment

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
icon
Concept explainers
Question
1.
The two mass spectra below correspond to two isomers of C5H10O2: methyl
butanoate and valeric acid. Match the spectrum with the appropriate compound. Place the
m/z ratio and the structures (show all atoms) for the labeled fragments in the table below.
100 -
Compound
MS-NU-1708
Methyl butanoate
80 -
1
60 -
40 -
CH3
2
H3C
20 -
10
20
30
40
50
60
70
80
90
100
m/z
100 -
Compound
MS-NU-3125
3
80 -
Valeric acid
60 -
4
40 -
H3C
20 -
10
20
30
40
50
60
70
80
90
100
m/z
Fragment 1
Fragment 2
Fragment 3
Fragment 4
m/z
74
87
Fragment
Relative Intensity
Transcribed Image Text:1. The two mass spectra below correspond to two isomers of C5H10O2: methyl butanoate and valeric acid. Match the spectrum with the appropriate compound. Place the m/z ratio and the structures (show all atoms) for the labeled fragments in the table below. 100 - Compound MS-NU-1708 Methyl butanoate 80 - 1 60 - 40 - CH3 2 H3C 20 - 10 20 30 40 50 60 70 80 90 100 m/z 100 - Compound MS-NU-3125 3 80 - Valeric acid 60 - 4 40 - H3C 20 - 10 20 30 40 50 60 70 80 90 100 m/z Fragment 1 Fragment 2 Fragment 3 Fragment 4 m/z 74 87 Fragment Relative Intensity
The three compounds shown below are structural isomers of each other. Match
each compound with its corresponding mass spectrum and draw the fragment ion
corresponding to the base peak in each.
b.
а.
c.
с.
HO
100 -
Compound
80 -
60 -
Fragment
40-
20 -
10
20
30
40
50
60
70
80
90
m/z
100 -
Compound
HS-NU-0749
80 -
60-
Fragment
40 -
20 -
10
20
30
40
50
60
70
80
m/z
100 -
Compound
HS-NU-1103
80 -
60 -
Fragment
40 -
20 -
10
20
30
40
50
60
70
80
m/z
Relative
Intensity
Relative Intensity
Relative Intensity
Transcribed Image Text:The three compounds shown below are structural isomers of each other. Match each compound with its corresponding mass spectrum and draw the fragment ion corresponding to the base peak in each. b. а. c. с. HO 100 - Compound 80 - 60 - Fragment 40- 20 - 10 20 30 40 50 60 70 80 90 m/z 100 - Compound HS-NU-0749 80 - 60- Fragment 40 - 20 - 10 20 30 40 50 60 70 80 m/z 100 - Compound HS-NU-1103 80 - 60 - Fragment 40 - 20 - 10 20 30 40 50 60 70 80 m/z Relative Intensity Relative Intensity Relative Intensity
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 2 images

Blurred answer
Knowledge Booster
IR Spectroscopy of Organic Molecules
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY