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1. The irreversible, gas-phase catalytic reaction A + B → C requires adsorption of both reactants to the catalyst in order for the reaction to occur. As part of the reaction, the product, C, is formed in the gas phase. Hence, the reaction is irreversible because C does not adsorb to the catalyst. Suggest a mechanism and develop the rate law for this reaction, assuming that the surface reaction is the rate-limiting step.

1. The irreversible, gas-phase catalytic reaction A + B → C requires adsorption of both reactants to the catalyst in order for the reaction to occur. As part of the reaction, the product, C, is formed in the gas phase. Hence, the reaction is irreversible because C does not adsorb to the catalyst. Suggest a mechanism and develop the rate law for this reaction, assuming that the surface reaction is the rate-limiting step.

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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1. The irreversible, gas-phase catalytic reaction A + B → C requires adsorption of both reactants to the catalyst in order for the reaction to occur. As part of the reaction, the product, C, is formed in the gas phase. Hence, the reaction is irreversible because C does not adsorb to the catalyst. Suggest a mechanism and develop the rate law for this reaction, assuming that the surface reaction is the rate-limiting step.
Transcribed Image Text:1. The irreversible, gas-phase catalytic reaction A + B → C requires adsorption of both reactants to the catalyst in order for the reaction to occur. As part of the reaction, the product, C, is formed in the gas phase. Hence, the reaction is irreversible because C does not adsorb to the catalyst. Suggest a mechanism and develop the rate law for this reaction, assuming that the surface reaction is the rate-limiting step.
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