1. Show the products of the reductive amination reactions below: a) Acetone + NH3, followed by H2/Ni2 b) Acetone + CH3NH2, followed by LIBH3CN c) Acetone + (CH3)2NH, followed by LIBH3CN

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter19: Enolate Anions And Enamines
Section: Chapter Questions
Problem 19.48P
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1. Show the products of the reductive amination reactions below;
a) Acetone + NH3, followed by H2/Ni2
b) Acetone + CH3NH2, followed by LIBH3CN
c) Acetone + (CH3)2NH, followed by LIBH3CN
2.
Write the reaction and the names of the products formed in the reaction of aniline and
N-methylaniline with:
a) NaNO3+HCI followed by CuClI
b) NaNO3+HCI followed by Cu20, Cu2*, H20
Transcribed Image Text:1. Show the products of the reductive amination reactions below; a) Acetone + NH3, followed by H2/Ni2 b) Acetone + CH3NH2, followed by LIBH3CN c) Acetone + (CH3)2NH, followed by LIBH3CN 2. Write the reaction and the names of the products formed in the reaction of aniline and N-methylaniline with: a) NaNO3+HCI followed by CuClI b) NaNO3+HCI followed by Cu20, Cu2*, H20
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