1. Lithium acetylide, DMSO (SN2) 2. HgSO4, H2SO4, H20 Jot Figure 13: Reactions

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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**Figure 13: Reactions**

This figure illustrates two chemical reactions.

1. **First Reaction (Top):**
   - **Reactants:** 
     - Phenylacetylene 
     - Undergoes reaction with lithium acetylide in the presence of DMSO (Dimethyl sulfoxide) through an SN2 mechanism.
   - **Intermediate:** 
     - Subsequent treatment with HgSO₄, H₂SO₄, and H₂O.
   - **Product:** 
     - A phenyl ketone derivative.

2. **Second Reaction (Bottom):**
   - **Reactant:** 
     - A terminal alkyne with branched alkyl groups at both ends.
   - **Product:** 
     - An internal alkylalkene with a butadiene structure, indicating isomerization or double bond formation.

These reactions demonstrate typical transformations involving substitution, addition of reagents, and rearrangement in organic synthesis.
Transcribed Image Text:**Figure 13: Reactions** This figure illustrates two chemical reactions. 1. **First Reaction (Top):** - **Reactants:** - Phenylacetylene - Undergoes reaction with lithium acetylide in the presence of DMSO (Dimethyl sulfoxide) through an SN2 mechanism. - **Intermediate:** - Subsequent treatment with HgSO₄, H₂SO₄, and H₂O. - **Product:** - A phenyl ketone derivative. 2. **Second Reaction (Bottom):** - **Reactant:** - A terminal alkyne with branched alkyl groups at both ends. - **Product:** - An internal alkylalkene with a butadiene structure, indicating isomerization or double bond formation. These reactions demonstrate typical transformations involving substitution, addition of reagents, and rearrangement in organic synthesis.
**Learning Target 15**

**Criteria for satisfactory score**

Reactants, products, and reagents that complete a reaction scheme must be specific compounds, not generic categories. Reagents and structures must be valid Lewis structures.

**Tasks**

Complete the synthetic sequences by drawing products/substrates/reagents in empty spaces in reactions below.

*Note: Please ensure all chemical drawings accurately represent the chemical structure as intended for educational purposes.*
Transcribed Image Text:**Learning Target 15** **Criteria for satisfactory score** Reactants, products, and reagents that complete a reaction scheme must be specific compounds, not generic categories. Reagents and structures must be valid Lewis structures. **Tasks** Complete the synthetic sequences by drawing products/substrates/reagents in empty spaces in reactions below. *Note: Please ensure all chemical drawings accurately represent the chemical structure as intended for educational purposes.*
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