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1. Hg(OAc)2, H20 SoCl2 NaOH t-butoxide Jones PCC 2. NaBH4 2. H,O2, OH" .CI HO,

1. Hg(OAc)2, H20 SoCl2 NaOH t-butoxide Jones PCC 2. NaBH4 2. H,O2, OH" .CI HO,

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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What reagents are required to carry out the following part of the above synthesis?

The image depicts a chemical reaction scheme with reagents and conditions for transforming an alcohol into a chlorinated acyl compound. ### Reagents and Conditions: - **Reagents Available:** - SOCl₂ - NaOH - 1. BH₃*THF - 2. H₂O₂, OH⁻ - t-butoxide - Jones - PCC (Pyridinium chlorochromate) - 1. Hg(OAc)₂, H₂O - 2. NaBH₄ - **Initial Reactant:** - A simple alcohol: Ethanol - **Target Product:** - A chlorinated acyl compound: Acyl chloride ### Reaction Pathway: - The reaction begins with ethanol (EtOH) on the left, as the starting material. - An arrow indicates the conversion of the alcohol to the final product, an acyl chloride. ### Steps to Achieve Transformation: 1. Select an appropriate reagent to convert the alcohol to the acyl chloride. In this scheme, **SOCl₂** (thionyl chloride) is relevant for this conversion. 2. When applied to ethanol, SOCl₂ typically facilitates the replacement of the hydroxyl group (-OH) with a chlorine atom, resulting in an acyl chloride such as ethanoyl chloride. The reaction illustrates a transformation used frequently in organic synthesis, utilizing thionyl chloride as a classical reagent for converting alcohols into their corresponding acyl chlorides, which are useful intermediates for further chemical reactions.
Transcribed Image Text:The image depicts a chemical reaction scheme with reagents and conditions for transforming an alcohol into a chlorinated acyl compound. ### Reagents and Conditions: - **Reagents Available:** - SOCl₂ - NaOH - 1. BH₃*THF - 2. H₂O₂, OH⁻ - t-butoxide - Jones - PCC (Pyridinium chlorochromate) - 1. Hg(OAc)₂, H₂O - 2. NaBH₄ - **Initial Reactant:** - A simple alcohol: Ethanol - **Target Product:** - A chlorinated acyl compound: Acyl chloride ### Reaction Pathway: - The reaction begins with ethanol (EtOH) on the left, as the starting material. - An arrow indicates the conversion of the alcohol to the final product, an acyl chloride. ### Steps to Achieve Transformation: 1. Select an appropriate reagent to convert the alcohol to the acyl chloride. In this scheme, **SOCl₂** (thionyl chloride) is relevant for this conversion. 2. When applied to ethanol, SOCl₂ typically facilitates the replacement of the hydroxyl group (-OH) with a chlorine atom, resulting in an acyl chloride such as ethanoyl chloride. The reaction illustrates a transformation used frequently in organic synthesis, utilizing thionyl chloride as a classical reagent for converting alcohols into their corresponding acyl chlorides, which are useful intermediates for further chemical reactions.
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