Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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What reagents are required to carry out the following part of the above synthesis?
Transcribed Image Text:The image depicts a chemical reaction scheme with reagents and conditions for transforming an alcohol into a chlorinated acyl compound.
### Reagents and Conditions:
- **Reagents Available:**
- SOCl₂
- NaOH
- 1. BH₃*THF
- 2. H₂O₂, OH⁻
- t-butoxide
- Jones
- PCC (Pyridinium chlorochromate)
- 1. Hg(OAc)₂, H₂O
- 2. NaBH₄
- **Initial Reactant:**
- A simple alcohol: Ethanol
- **Target Product:**
- A chlorinated acyl compound: Acyl chloride
### Reaction Pathway:
- The reaction begins with ethanol (EtOH) on the left, as the starting material.
- An arrow indicates the conversion of the alcohol to the final product, an acyl chloride.
### Steps to Achieve Transformation:
1. Select an appropriate reagent to convert the alcohol to the acyl chloride. In this scheme, **SOCl₂** (thionyl chloride) is relevant for this conversion.
2. When applied to ethanol, SOCl₂ typically facilitates the replacement of the hydroxyl group (-OH) with a chlorine atom, resulting in an acyl chloride such as ethanoyl chloride.
The reaction illustrates a transformation used frequently in organic synthesis, utilizing thionyl chloride as a classical reagent for converting alcohols into their corresponding acyl chlorides, which are useful intermediates for further chemical reactions.
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