1. Given the following molecules: (a) BF3; (b) ICl3; (c) SF4 i. Draw the best Lewis structure ii. Indicate the formal charge of each atom iii. Determine the EDG and MG iv. Indicate if the molecule follows the octet rule. If it does not follow the octet rule, indicate the type of octet rule exception each molecule exhibits. 2. 2. Methionine is an amino acid found in proteins. Copy the Lewis structure of this compound and indicate the hybridization type of each carbon, oxygen, the nitrogen, and the sulfur atom. 3.Given the following molecules: (a) CO2 (b) H2O i. Draw the most stable Lewis structure of the following molecules. ii. Show the process of promotion and hybridization of the orbitals iii. Show the overlap of orbitals of using VBT. 4. Are these statements true or false? Correct the underlined phrase for false statements. (a) two σ bonds comprise a double bond; (b) a triple bond consists of one π bond and two σ bonds; (c) bonds formed from atomic s orbitals are always σ bonds;
Formal Charges
Formal charges have an important role in organic chemistry since this concept helps us to know whether an atom in a molecule is neutral/bears a positive or negative charge. Even if some molecules are neutral, the atoms within that molecule need not be neutral atoms.
Polarity Of Water
In simple chemical terms, polarity refers to the separation of charges in a chemical species leading into formation of two polar ends which are positively charged end and negatively charged end. Polarity in any molecule occurs due to the differences in the electronegativities of the bonded atoms. Water, as we all know has two hydrogen atoms bonded to an oxygen atom. As oxygen is more electronegative than hydrogen thus, there exists polarity in the bonds which is why water is known as a polar solvent.
Valence Bond Theory Vbt
Valence bond theory (VBT) in simple terms explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. It gives a quantum mechanical approach to the formation of covalent bonds with the help of wavefunctions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.
1. Given the following molecules: (a) BF3; (b) ICl3; (c) SF4
i. Draw the best Lewis structure
ii. Indicate the formal charge of each atom
iii. Determine the EDG and MG
iv. Indicate if the molecule follows the octet rule. If it does not follow the octet rule,
indicate the type of octet rule exception each molecule exhibits.
2. 2. Methionine is an amino acid found in proteins. Copy the Lewis structure of this compound and indicate the hybridization type of each carbon, oxygen, the nitrogen, and the sulfur atom.
3.Given the following molecules: (a) CO2 (b) H2O
i. Draw the most stable Lewis structure of the following molecules.
ii. Show the process of promotion and hybridization of the orbitals
iii. Show the overlap of orbitals of using
4. Are these statements true or false? Correct the underlined phrase for false statements.
(a) two σ bonds comprise a double bond;
(b) a triple bond consists of one π bond and two σ bonds;
(c) bonds formed from atomic s orbitals are always σ bonds;
(d) a π bond consists of two pairs of electrons;
5. Given the following diatomic molecules: (a) Be22– (b) N2 2+
i. Draw the MO Diagram
ii. write the MO electron configuration (combined notation)
iii. calculate bond order
iv. determine number of bonds
v. determine the magnetic property
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