1. Determination of heat capacity of calorimeter: 50.0 mL. H2O at the initial temperature of 23.5 °C is added to a calorimeter (coffee cup) and stirred and kept for 5 minutes. Then 50.0 mL. of hot water at the temperature of 98.0 °C is added to the calorimeter contained the 50.0 mL. H2O at 23.5 °C. The temperature of the mixture is recorded every 30 second, the following data is obtained:

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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Hint: This is the diluted : heat capacity = 3.184 J / g °C and D = 1.00 g/ mole
Heat of reaction = - (heat of solution) - heat of calorimetry
c. Calculate the heat of reaction for the following chemical reaction:
NaOH (s) + HC1(aq) --------→ NaC(aq) + H2O(1)
Using the following reactions:
NaOH(s) -
-→ NaOH(aq).
AH = -102 kj / mole
NaOH(aq) + HCl(aq) --
calculations.
-→ NaCl(aq) + H2O(1). use the heat of reaction from your
- -
Transcribed Image Text:Hint: This is the diluted : heat capacity = 3.184 J / g °C and D = 1.00 g/ mole Heat of reaction = - (heat of solution) - heat of calorimetry c. Calculate the heat of reaction for the following chemical reaction: NaOH (s) + HC1(aq) --------→ NaC(aq) + H2O(1) Using the following reactions: NaOH(s) - -→ NaOH(aq). AH = -102 kj / mole NaOH(aq) + HCl(aq) -- calculations. -→ NaCl(aq) + H2O(1). use the heat of reaction from your - -
Chem. 1A : Thermochemistry
1. Determination of heat capacity of calorimeter:
50.0 mL. H2O at the initial temperature of 23.5 °C is added to a calorimeter (coffee cup) and
stirred and kept for 5 minutes. Then 50.0 mL. of hot water at the temperature of 98.0 °C is
added to the calorimeter contained the 50.0 mL. H2O at 23.5 °C. The temperature of the
mixture is recorded every 30 second, the following data is obtained:
Time in second
Temperature in °C
30
55.0
60
50.0
90
45.5
120
42.0
150
38.0
180
37.5
210
37.5
240
37.0
270
37.0
300
37.0
330
37.0
D of H2O = 1.00 g/ mL.
Heat capacity of H2O (1) = 4.184 J/ g °C
a. Plot temperature vs. time to get the final temperature.
b. Calculate the heat capacity of the calorimeter.
Hint: the heat lost by hot water = heat gained by cold water + heat gained by calorimeter
2. Determination heat of reaction.
50.0 mL. of 0.100 M NaOH(aq) at the temperature of 22.0 °C is added to a calorimeter
(coffee cup). Then 50.0 mL. of HCl(aq) at the temperature of 21.0 °C is added to the
calorimeter containing NaOH(aq). The temperature is measured every 30 seconds , the
following data is obtained:
Time in second
Temperature in °C
30
25.0
60
26.5
90
28.0
120
29.5
150
29.0
180
29.5
210
29.5
a. Plot temperature vs. time to get the final temperature.
b. Calculate the heat of reaction in kJ/ mole
Transcribed Image Text:Chem. 1A : Thermochemistry 1. Determination of heat capacity of calorimeter: 50.0 mL. H2O at the initial temperature of 23.5 °C is added to a calorimeter (coffee cup) and stirred and kept for 5 minutes. Then 50.0 mL. of hot water at the temperature of 98.0 °C is added to the calorimeter contained the 50.0 mL. H2O at 23.5 °C. The temperature of the mixture is recorded every 30 second, the following data is obtained: Time in second Temperature in °C 30 55.0 60 50.0 90 45.5 120 42.0 150 38.0 180 37.5 210 37.5 240 37.0 270 37.0 300 37.0 330 37.0 D of H2O = 1.00 g/ mL. Heat capacity of H2O (1) = 4.184 J/ g °C a. Plot temperature vs. time to get the final temperature. b. Calculate the heat capacity of the calorimeter. Hint: the heat lost by hot water = heat gained by cold water + heat gained by calorimeter 2. Determination heat of reaction. 50.0 mL. of 0.100 M NaOH(aq) at the temperature of 22.0 °C is added to a calorimeter (coffee cup). Then 50.0 mL. of HCl(aq) at the temperature of 21.0 °C is added to the calorimeter containing NaOH(aq). The temperature is measured every 30 seconds , the following data is obtained: Time in second Temperature in °C 30 25.0 60 26.5 90 28.0 120 29.5 150 29.0 180 29.5 210 29.5 a. Plot temperature vs. time to get the final temperature. b. Calculate the heat of reaction in kJ/ mole
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