1. Consider the coordination compound Na4[Fe(ONO)2(Ox)2]. A. Write the systematic name of the compound. B. Indicate the (i) oxidation state, (ii) coordination number, and (iii) type of hybridization of the central metal in the complex anion. C. Considering the geometry of the complex anion and the ligand field strength, show how the five d orbitals split and how the d electrons are distributed in these orbitals. Label each d orbital (e.g. dxy). D. Is the complex anion paramagnetic? Justify your answer. E. Linkage isomerism is possible for the complex anion. Write the chemical formula of the three possible linkage isomers. F. The complex anion has two geometric isomers, cis and trans. One of these two exhibits optical isomerism. Draw the structures of the enantiomeric pair. G. Malonate (C3H₂04) is a ligand that is similar to oxalate (C₂04). Both are dicarboxylate anions that are capable of bidentate mode of binding through two oxygen atoms. If the oxalate ligands in Na4[Fe(ONO)2(ox)₂] are replaced with malonate ligands, what is the systematic name of the resulting coordination compound?

1. Consider the coordination compound Na4[Fe(ONO)2(Ox)2]. A. Write the systematic name of the compound. B. Indicate the (i) oxidation state, (ii) coordination number, and (iii) type of hybridization of the central metal in the complex anion. C. Considering the geometry of the complex anion and the ligand field strength, show how the five d orbitals split and how the d electrons are distributed in these orbitals. Label each d orbital (e.g. dxy). D. Is the complex anion paramagnetic? Justify your answer. E. Linkage isomerism is possible for the complex anion. Write the chemical formula of the three possible linkage isomers. F. The complex anion has two geometric isomers, cis and trans. One of these two exhibits optical isomerism. Draw the structures of the enantiomeric pair. G. Malonate (C3H₂04) is a ligand that is similar to oxalate (C₂04). Both are dicarboxylate anions that are capable of bidentate mode of binding through two oxygen atoms. If the oxalate ligands in Na4[Fe(ONO)2(ox)₂] are replaced with malonate ligands, what is the systematic name of the resulting coordination compound?

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Concept explainers

Atomic Structure

The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.

Shape of the D Orbital

Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.

Question

1. Consider the coordination compound Na4[Fe(ONO)2(Ox)2].
A. Write the systematic name of the compound.
B. Indicate the (i) oxidation state, (ii) coordination number, and (iii) type of hybridization of the central
metal in the complex anion.
C. Considering the geometry of the complex anion and the ligand field strength, show how the five d
orbitals split and how the d electrons are distributed in these orbitals. Label each d orbital (e.g. dxy).
D. Is the complex anion paramagnetic? Justify your answer.
E. Linkage isomerism is possible for the complex anion. Write the chemical formula of the three possible
linkage isomers.
F. The complex anion has two geometric isomers, cis and trans. One of these two exhibits optical
isomerism. Draw the structures of the enantiomeric pair.
G. Malonate (C3H₂04) is a ligand that is similar to oxalate (C₂04). Both are dicarboxylate anions that
are capable of bidentate mode of binding through two oxygen atoms. If the oxalate ligands in
Na4[Fe(ONO)2(ox)₂] are replaced with malonate ligands, what is the systematic name of the resulting
coordination compound?

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