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*The drug Nipride, Naz[Fe(CN)5NO], is an inorganic complex which is used as a source of NO to lower blood pressure during surgery. a. For the complex [Fe(CN)5NO]²-, draw the orbital diagram for the d-orbitals, indicate whether the complex is high-spin or low-spin, and give the number of unpaired electrons. b. The [Fe(CN)5NO]²- complex is red-violet in color (“ruby red"), while the similar complex [Fe(CN)6]³- is red-orange in color (“bright red"). The CN- ligand is a strong-field ligand. By comparison, the NO ligand is: much weaker slightly weaker slightly stronger much stronger c. Briefly explain your choice using the language of crystal field theory.

*The drug Nipride, Naz[Fe(CN)5NO], is an inorganic complex which is used as a source of NO to lower blood pressure during surgery. a. For the complex [Fe(CN)5NO]²-, draw the orbital diagram for the d-orbitals, indicate whether the complex is high-spin or low-spin, and give the number of unpaired electrons. b. The [Fe(CN)5NO]²- complex is red-violet in color (“ruby red"), while the similar complex [Fe(CN)6]³- is red-orange in color (“bright red"). The CN- ligand is a strong-field ligand. By comparison, the NO ligand is: much weaker slightly weaker slightly stronger much stronger c. Briefly explain your choice using the language of crystal field theory.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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*The drug Nipride, Naz[Fe(CN)5NO], is an inorganic complex which is used as a source of NO to lower blood pressure during surgery. a. For the complex [Fe(CN)5NO]²-, draw the orbital diagram for the d-orbitals, indicate whether the complex is high-spin or low-spin, and give the number of unpaired electrons. b. The [Fe(CN)5NO]²- complex is red-violet in color (“ruby red"), while the similar complex [Fe(CN)«]3- is red-orange in color (“bright red"). The CN- ligand is a strong-field ligand. By comparison, the NO ligand is: much weaker slightly weaker slightly stronger much stronger c. Briefly explain your choice using the language of crystal field theory.
Transcribed Image Text:*The drug Nipride, Naz[Fe(CN)5NO], is an inorganic complex which is used as a source of NO to lower blood pressure during surgery. a. For the complex [Fe(CN)5NO]²-, draw the orbital diagram for the d-orbitals, indicate whether the complex is high-spin or low-spin, and give the number of unpaired electrons. b. The [Fe(CN)5NO]²- complex is red-violet in color (“ruby red"), while the similar complex [Fe(CN)«]3- is red-orange in color (“bright red"). The CN- ligand is a strong-field ligand. By comparison, the NO ligand is: much weaker slightly weaker slightly stronger much stronger c. Briefly explain your choice using the language of crystal field theory.
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