1. Acid-base equilibrium a. Draw the major resonance contributors of the product structures for each acid-base reaction below. b. Use the pKa data from lecture to estimate the pKa of each acid / conjugate acid. Calculate Keq for each reaction and draw the corresponding equilibrium arrow. c. i H acid :pka = NH acid pka = 0=60=0 HO-S-OH acid pka = NLi base ONa base NH base Kea (equilibrium arrow) Keg (equilibrium arrow) Keq (equilibrium arrow) NLI conjugate base conjugate base conjugate base conjugate acid pka = conjugate acid pka = conjugate acid 1 pka =

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1. Acid-base equilibrium
a.. Draw the major resonance contributors of the product structures for each acid-base reaction below.
b. Use the pKa data from lecture to estimate the pKa of each acid / conjugate acid.
Calculate Keq for each reaction and draw the corresponding equilibrium arrow.
c.
i
H
acid
1 pka =
ΝΗ
acid
pka =
O=S=
HO-S-OH
O
acid
ipka =
NLi
base
ONa
base
NH
人
base
(equilibrium arrow)
Kea
1
1
(equilibrium arrow)
B
Keg
Keg
=!
(equilibrium arrow)
1
T
1
1
1
1
1
1
1
1
I
1
NLI
e
conjugate base
conjugate base
conjugate base
1
H
conjugate acid
¦pka =
conjugate acid
pka =
conjugate acid
pka =
1
Transcribed Image Text:1. Acid-base equilibrium a.. Draw the major resonance contributors of the product structures for each acid-base reaction below. b. Use the pKa data from lecture to estimate the pKa of each acid / conjugate acid. Calculate Keq for each reaction and draw the corresponding equilibrium arrow. c. i H acid 1 pka = ΝΗ acid pka = O=S= HO-S-OH O acid ipka = NLi base ONa base NH 人 base (equilibrium arrow) Kea 1 1 (equilibrium arrow) B Keg Keg =! (equilibrium arrow) 1 T 1 1 1 1 1 1 1 1 I 1 NLI e conjugate base conjugate base conjugate base 1 H conjugate acid ¦pka = conjugate acid pka = conjugate acid pka = 1
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