1. a. What is the pH of a solution prepared by adding 25.0 mL of 0.10 M acetic acid (Ka ) and 20-x: = 1.8 x 10-5) and 20.0 mL of 0.10 M sodium acetate? Dis tinn
1. a. What is the pH of a solution prepared by adding 25.0 mL of 0.10 M acetic acid (Ka ) and 20-x: = 1.8 x 10-5) and 20.0 mL of 0.10 M sodium acetate? Dis tinn
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Explain why the solution prepared in part a is a buffer splution. Hint: re read the first page of this experiment:
![Answer the following questions (la-d and 2a-c). Make sure you place the prelab pages on the
instructor's bench.
These calculations relate to the lab. You will not be able to do the lab without having
these calculations done first!
Given:
-CH,COOH
= 25.0mL
-ICHCO0H]
= 0.10M
Ka=1.8x/0-5"
- NACH, C00
= 20.0 mL
-INACH3CO0]
= 10.0M
= [CH3C00]
1. a. What is the pH of a solution prepared by adding 25.0 mL of 0.10 M acetic acid (Ka
= 1.8 x 105) and 20.0, mL of 0.10 M sodium acetate?
Dissociation Rxn:
CH3CO0H + H20= CHg C 0O+Hg0+
Base Conugate Con usate
Acid
Base
6Using Equation:
pH=pKqt log Ilonj. Broel
Acid]
Henderson-Hasselkach
[Conj. Basel
F(20.0mL)(0.10mol)
(25.0+20.0) mL
pH = -log(1.8x10-9) + log T 25.0 umL (onO kap
(25.0+20.0) mL
pH=4.4478](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Ffbfefd57-6cd5-45bf-b890-c343c2fceb41%2F551599e3-7a2c-4a99-a84f-e5112c517956%2Fev6bv41_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Answer the following questions (la-d and 2a-c). Make sure you place the prelab pages on the
instructor's bench.
These calculations relate to the lab. You will not be able to do the lab without having
these calculations done first!
Given:
-CH,COOH
= 25.0mL
-ICHCO0H]
= 0.10M
Ka=1.8x/0-5"
- NACH, C00
= 20.0 mL
-INACH3CO0]
= 10.0M
= [CH3C00]
1. a. What is the pH of a solution prepared by adding 25.0 mL of 0.10 M acetic acid (Ka
= 1.8 x 105) and 20.0, mL of 0.10 M sodium acetate?
Dissociation Rxn:
CH3CO0H + H20= CHg C 0O+Hg0+
Base Conugate Con usate
Acid
Base
6Using Equation:
pH=pKqt log Ilonj. Broel
Acid]
Henderson-Hasselkach
[Conj. Basel
F(20.0mL)(0.10mol)
(25.0+20.0) mL
pH = -log(1.8x10-9) + log T 25.0 umL (onO kap
(25.0+20.0) mL
pH=4.4478

Transcribed Image Text:Prelab: Before coming to lab, outline the procedures and neatly prepare the following
data tables in your lab notebook.
Data Table 1: Testing of Buffer Solution and Water
Initial pH
Solution
After 5.0 mL HCI
After 5.0 mL NAOH
HC2H3O2/ C2H;O2
H2O
Data Table 2: Ammonia Buffers
# Drops of 1.0 MHCI
to reach pH =8.00
# Drops of 1.0 M NAOH to
reach pH = 10.00
Buffer
Note to students:
This is how you'll count
1) NH3 NH4 ag solutions
your drops:
Make thase boxes plenty lrge
you will record many deops
HITI
l etc...
Some solution may équire
uprds of I00 ops or more
Make these boxes plenty
large, you will record
drops
many
2) NH3/solid NHẠC1
Some solution may require
upwards of 100 drops or
more
3) NH: titrated with HCI
Expert Solution

Step 1
25.0 mL of 0.1 M acetic acid and 20 ml of 0.1 M sodium acetate are mixed.
Acetic acid is a weak acid and acetate is a salt obtained by the neutralization of weak acetic acid and a strong base. A mixture of weak acid and its salt with strong base act as acidic buffer.
pH of a buffer can be calculated using the expression:
Ka = 1.8 * 10-5
pKa = -log(1.8 * 10-5)
= 5 - log 1.8
= 5 - 0.2553
= 4.7447
= 4.74
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