1. 2. HO H 1. SOCI₂ a = Proton transfer b = Lewis acid/base c = Radical chain substitution d = Radical chain addition 2. P(n-Bu)3 P(n-Bu)4 e = Electrophilic addition f = E1 Elimination g = E2 Elimination Br SO₂ + HCI Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - j for your answers. h = SN1 Nucleophilic substitution i = SN2 Nucleophilic substitution j = Electrophilic aromatic substitution
1. 2. HO H 1. SOCI₂ a = Proton transfer b = Lewis acid/base c = Radical chain substitution d = Radical chain addition 2. P(n-Bu)3 P(n-Bu)4 e = Electrophilic addition f = E1 Elimination g = E2 Elimination Br SO₂ + HCI Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - j for your answers. h = SN1 Nucleophilic substitution i = SN2 Nucleophilic substitution j = Electrophilic aromatic substitution
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:1.
2.
HO H
1.
Br
2.
+
SOCI₂
a = Proton transfer
b = Lewis acid/base
C = Radical chain substitution
d Radical chain addition
P(n-Bu)3
P(n-Bu)4
e =
f = E1 Elimination
g = E2 Elimination
Electrophilic addition
H CI
Br
+
SO₂ + HCI
Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the
letters a j for your answers.
h = SN1 Nucleophilic substitution
i = SN2 Nucleophilic substitution
j = Electrophilic aromatic substitution
Expert Solution
Step 1 Theory
Sn1 nucleophilic substitution:
1. It follow first order kinetics.
2. Rate of reaction depends only on concentration of alkyl halide.
3. The reaction proceed through carbocation intermediate.
4. There is racemisation of products.
5. Rate of reaction increases as follows:
1°<2°<3°
Sn2 nucleophilic substitution:
1. It follow second order kinetics.
2. Rate of reaction depends on the concentration of alkyl halide and nucleophile.
3. There is inversion of configuration.
4. Rate of reaction increases as follows:
3°<2°<1
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