1. 2-bromobutane + cyclohexanol + NaH à (major product) c. 2-butoxycyclohexane a.. 2-butene b. 1-butene d. no reaction e. something else! 2. t-butylbromide + sodium ethoxide in ethanol à (major product) a. 2-methylpropene reaction e. something else! b. t-butyl ethyl ether c. 1-methylbutene d. no 3. potassium t-butoxide + 1-bromobutane in t-butyl alcohol room temperature à (major product) a. 1-butene b. butyl t-butyl ether c. 2-methylpropene d. no reaction e. something else! 4. t-butyl bromide + boiling hot water à (major product) a. 2-methylpropene reaction e. something else! b. t-butyl ethyl ether c. t-butanol d. no 5. 2-chloropropane + acetic acid (2 eq) / KOH (1 eq) / DMF à(major product) c. а. b. с. d. no reaction e. something else! Br KOH / DMSO
1. 2-bromobutane + cyclohexanol + NaH à (major product) c. 2-butoxycyclohexane a.. 2-butene b. 1-butene d. no reaction e. something else! 2. t-butylbromide + sodium ethoxide in ethanol à (major product) a. 2-methylpropene reaction e. something else! b. t-butyl ethyl ether c. 1-methylbutene d. no 3. potassium t-butoxide + 1-bromobutane in t-butyl alcohol room temperature à (major product) a. 1-butene b. butyl t-butyl ether c. 2-methylpropene d. no reaction e. something else! 4. t-butyl bromide + boiling hot water à (major product) a. 2-methylpropene reaction e. something else! b. t-butyl ethyl ether c. t-butanol d. no 5. 2-chloropropane + acetic acid (2 eq) / KOH (1 eq) / DMF à(major product) c. а. b. с. d. no reaction e. something else! Br KOH / DMSO
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![1. 2-bromobutane + cyclohexanol + NaH à (major product)
c. 2-butoxycyclohexane
a.. 2-butene
reaction
b. 1-butene
d. no
e. something else!
2. t-butylbromide + sodium ethoxide in ethanol à (major product)
a. 2-methylpropene
reaction
b. t-butyl ethyl ether
c. 1-methylbutene
d. no
e. something else!
3. potassium t-butoxide + 1-bromobutane in t-butyl alcohol room
temperature à (major product)
a. 1-butene
reaction
c. 2-methylpropene d. no
b. butyl t-butyl ether
e. something else!
4. t-butyl bromide + boiling hot water à (major product)
a. 2-methylpropene
reaction
b. t-butyl ethyl ether
c. t-butanol
d. no
e. something else!
5. 2-chloropropane + acetic acid (2 eq) / KOH (1 eq) / DMF à(major
product)
c.
b.
d. no reaction
e. something
а.
HO.
else!
Br
KOH / DMSO
6.
b. 2-methyl-1-propanol
d. 1,2-
a. 2-methylpropene
propanediene
c. no reaction
e. something else!
7. cyclopentanol+ NaH + DMSO + bromopropane à(major product)
a. cyclopentene
reaction
b. propene
e. something else!!
c. propyl cyclopentyl ether
d. no
8. 2-bromo-3-methylbutane + KOH / DMSO à(major product)
a. 2-methyl-1-butene
d. no reaction
b. 2-methyl-2-butene c. 3-methyl-2-butanol
e. something else!!
9. 2-chloro-3-methylbutane + KI/ DMSO à(major product)
a. 2-methyl-1-butene
d. no rxn
b. 2-methyl-2-butene
c. 3-methyl-2-iodobutane
e. something else!!
10. (S)-2-iodobutane + NaN3 / DMF à (major product)
a. V
b.
d. V
e. no rxn
f. something else!!
11. cyclohexene + NBS/ CCI, / light followed by K* t-butoxide / t-butanol
with heating à
a. cyclohexene b. 1,3-cyclohexadiene
cyclohexane e. something else!
c. 1,2-cyclohexadiene d.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F6836cbec-f747-48e0-a965-974dd3713896%2Fa0dd186a-674c-47ae-8a75-979d7f9e9b6b%2Fmhmdfws_processed.jpeg&w=3840&q=75)
Transcribed Image Text:1. 2-bromobutane + cyclohexanol + NaH à (major product)
c. 2-butoxycyclohexane
a.. 2-butene
reaction
b. 1-butene
d. no
e. something else!
2. t-butylbromide + sodium ethoxide in ethanol à (major product)
a. 2-methylpropene
reaction
b. t-butyl ethyl ether
c. 1-methylbutene
d. no
e. something else!
3. potassium t-butoxide + 1-bromobutane in t-butyl alcohol room
temperature à (major product)
a. 1-butene
reaction
c. 2-methylpropene d. no
b. butyl t-butyl ether
e. something else!
4. t-butyl bromide + boiling hot water à (major product)
a. 2-methylpropene
reaction
b. t-butyl ethyl ether
c. t-butanol
d. no
e. something else!
5. 2-chloropropane + acetic acid (2 eq) / KOH (1 eq) / DMF à(major
product)
c.
b.
d. no reaction
e. something
а.
HO.
else!
Br
KOH / DMSO
6.
b. 2-methyl-1-propanol
d. 1,2-
a. 2-methylpropene
propanediene
c. no reaction
e. something else!
7. cyclopentanol+ NaH + DMSO + bromopropane à(major product)
a. cyclopentene
reaction
b. propene
e. something else!!
c. propyl cyclopentyl ether
d. no
8. 2-bromo-3-methylbutane + KOH / DMSO à(major product)
a. 2-methyl-1-butene
d. no reaction
b. 2-methyl-2-butene c. 3-methyl-2-butanol
e. something else!!
9. 2-chloro-3-methylbutane + KI/ DMSO à(major product)
a. 2-methyl-1-butene
d. no rxn
b. 2-methyl-2-butene
c. 3-methyl-2-iodobutane
e. something else!!
10. (S)-2-iodobutane + NaN3 / DMF à (major product)
a. V
b.
d. V
e. no rxn
f. something else!!
11. cyclohexene + NBS/ CCI, / light followed by K* t-butoxide / t-butanol
with heating à
a. cyclohexene b. 1,3-cyclohexadiene
cyclohexane e. something else!
c. 1,2-cyclohexadiene d.
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