1. 2-bromobutane + cyclohexanol + NaH à (major product) c. 2-butoxycyclohexane a.. 2-butene b. 1-butene d. no reaction e. something else! 2. t-butylbromide + sodium ethoxide in ethanol à (major product) a. 2-methylpropene reaction e. something else! b. t-butyl ethyl ether c. 1-methylbutene d. no 3. potassium t-butoxide + 1-bromobutane in t-butyl alcohol room temperature à (major product) a. 1-butene b. butyl t-butyl ether c. 2-methylpropene d. no reaction e. something else! 4. t-butyl bromide + boiling hot water à (major product) a. 2-methylpropene reaction e. something else! b. t-butyl ethyl ether c. t-butanol d. no 5. 2-chloropropane + acetic acid (2 eq) / KOH (1 eq) / DMF à(major product) c. а. b. с. d. no reaction e. something else! Br KOH / DMSO
1. 2-bromobutane + cyclohexanol + NaH à (major product) c. 2-butoxycyclohexane a.. 2-butene b. 1-butene d. no reaction e. something else! 2. t-butylbromide + sodium ethoxide in ethanol à (major product) a. 2-methylpropene reaction e. something else! b. t-butyl ethyl ether c. 1-methylbutene d. no 3. potassium t-butoxide + 1-bromobutane in t-butyl alcohol room temperature à (major product) a. 1-butene b. butyl t-butyl ether c. 2-methylpropene d. no reaction e. something else! 4. t-butyl bromide + boiling hot water à (major product) a. 2-methylpropene reaction e. something else! b. t-butyl ethyl ether c. t-butanol d. no 5. 2-chloropropane + acetic acid (2 eq) / KOH (1 eq) / DMF à(major product) c. а. b. с. d. no reaction e. something else! Br KOH / DMSO
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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1. **2-bromobutane + cyclohexanol + NaH → (major product)**
- a. 2-butene
- b. 1-butene
- c. 2-butoxycyclohexane
- d. no reaction
- e. something else!
2. **t-butyl bromide + sodium ethoxide in ethanol → (major product)**
- a. 2-methylpropene
- b. t-butyl ethyl ether
- c. 1-methylbutene
- d. no reaction
- e. something else!
3. **potassium t-butoxide + 1-bromobutane in t-butyl alcohol at room temperature → (major product)**
- a. 1-butene
- b. butyl t-butyl ether
- c. 2-methylpropene
- d. no reaction
- e. something else!
4. **t-butyl bromide + boiling hot water → (major product)**
- a. 2-methylpropene
- b. t-butyl ethyl ether
- c. t-butanol
- d. no reaction
- e. something else!
5. **2-chloropropane + acetic acid (2 eq) / KOH (1 eq) / DMF → (major product)**
- a. (a hydrocarbon structure)
- b. (an ester structure)
- c. (an alcohol structure)
- d. no reaction
- e. something else!
6. **(Illustration of a reaction involving KOH / DMSO)**
- a. 2-methylpropene
- b. 2-methyl-1-propanol
- c. no reaction
- d. 1,2-propadiene
- e. something else!
7. **cyclopentanol + NaH + DMSO + bromopropane → (major product)**
- a. cyclopentene
- b. propene
- c. propyl cyclopentyl ether
- d. no reaction
- e. something else!
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