1) Naphthalene reacts about 20x faster in nitration than does benzene. Looking at the resonance forms of the intermediate, can you explain the reasoning. HNO, H.SO 60 °C HNO 25 °C NO₂
1) Naphthalene reacts about 20x faster in nitration than does benzene. Looking at the resonance forms of the intermediate, can you explain the reasoning. HNO, H.SO 60 °C HNO 25 °C NO₂
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![1) Naphthalene reacts about 20x faster in nitration than does
benzene. Looking at the resonance forms of the intermediate,
can you explain the reasoning.
HNO,
H₂SO
60 °C
HNO,
25 °C
NO₂
2) We saw that sulfonation is reversible and the SO, can be
removed in sulfuric acid with heat. Alkylation can also be
reversible, but not for all alkyl benzenes. Which of the following
alkylbenzenes will most easily dealkylate - and why?
H₂C-
CH₂ H.C. CH₂
H₂C
8 6 6 6
3) What is the structure of benzyne and what are two reactions
that can be run with benzyne?](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Ffd285342-6d44-4465-a8e0-815a2c12e9bc%2Fdce59bd7-9a5f-449f-a078-a4d791c6940c%2Fqsxukvj_processed.jpeg&w=3840&q=75)
Transcribed Image Text:1) Naphthalene reacts about 20x faster in nitration than does
benzene. Looking at the resonance forms of the intermediate,
can you explain the reasoning.
HNO,
H₂SO
60 °C
HNO,
25 °C
NO₂
2) We saw that sulfonation is reversible and the SO, can be
removed in sulfuric acid with heat. Alkylation can also be
reversible, but not for all alkyl benzenes. Which of the following
alkylbenzenes will most easily dealkylate - and why?
H₂C-
CH₂ H.C. CH₂
H₂C
8 6 6 6
3) What is the structure of benzyne and what are two reactions
that can be run with benzyne?
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