Answered: 1) In the following reaction,…

1) In the following reaction, substituent X was varied between electron donating and electron withdrawing. Would a positive or negative Hammett reaction constant o value be

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter4: Organic Compounds: Cycloalkanes And Their Stereochemistry

Section4.SE: Something Extra

Problem 51AP

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Concept explainers

Alkanes and Cycloalkanes

Alkanes are saturated organic compounds which are made up of C and H atoms. Alkanes have the general formula of CnH2n+2. Alkane contains sp3 hybridized carbon atoms with four sigmas (σ) bonds & every hydrogen atom is connected with one of the carbon atoms. The size of the alkane could be determined by the number of carbon atoms located in it.

Question

Please don't provide handwriting solution

Learning Activities
1) In the following reaction, substituent X was
varied between electron donating and electron
withdrawing. Would a positive or negative
Hammett reaction constant, p, value be
expected for this equilibrium? Explain your
reasoning.
X
H+
H

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Step 2: Hammett equation

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Step 3: Nature of Substitutent X

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Step 4: Sign of X

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