[1] Given: CH,(g) + H2O(g) CO(g) + 3H2(g). AH° for the reaction is +206.1 kJ/mol, while AS° is +215 J/K•mol. Calculate AG° for this reaction at 25.0°C and determine whether it is spontaneous at that temperature.

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AG°= - RT In Keq and
In Keg =-
or Keg = 04G®/RT
[1] Given: CH4(g) + H2O(g) → CO(g) + 3H2(g). AH° for the reaction is +206.1 kJ/mol, while AS° is +215 J/K•mol.
Calculate AG° for this reaction at 25.0°C and determine whether it is spontaneous at that temperature.
[2] [a] The forward reaction is spontaneous for a particular reversible reaction. What can you conclude about the reverse
reaction?
[b] What does the sign of the free energy have to be such that a reaction is spontaneous?
AG =
[c] [i] Under what conditions of enthalpy and entropy change is a reaction always spontaneous? AH=,
[ii] Under what conditions of enthalpy and entropy change is a reaction never spontaneous?
AS =
ΔΗ-
AS =
[d] If the entropy change is unfavorable for a certain reaction, is the reaction more likely to be spontaneous at a high
temperature or a low temperature?
[e] If the enthalpy change is unfavorable, but the entropy change is favorable, would a high temperature or a low
temperature
more likely to lead to a spontaneous reaction?
[3] For the reaction C,H2(g) + 2H2(g) ) → C2H6(g), AG°(C,H2) = +209.2kJ/mol and AG°(C2H6) = -32.89 kJ/mol at
25.0°C. What is Keg for this reaction?
Transcribed Image Text:AG°= - RT In Keq and In Keg =- or Keg = 04G®/RT [1] Given: CH4(g) + H2O(g) → CO(g) + 3H2(g). AH° for the reaction is +206.1 kJ/mol, while AS° is +215 J/K•mol. Calculate AG° for this reaction at 25.0°C and determine whether it is spontaneous at that temperature. [2] [a] The forward reaction is spontaneous for a particular reversible reaction. What can you conclude about the reverse reaction? [b] What does the sign of the free energy have to be such that a reaction is spontaneous? AG = [c] [i] Under what conditions of enthalpy and entropy change is a reaction always spontaneous? AH=, [ii] Under what conditions of enthalpy and entropy change is a reaction never spontaneous? AS = ΔΗ- AS = [d] If the entropy change is unfavorable for a certain reaction, is the reaction more likely to be spontaneous at a high temperature or a low temperature? [e] If the enthalpy change is unfavorable, but the entropy change is favorable, would a high temperature or a low temperature more likely to lead to a spontaneous reaction? [3] For the reaction C,H2(g) + 2H2(g) ) → C2H6(g), AG°(C,H2) = +209.2kJ/mol and AG°(C2H6) = -32.89 kJ/mol at 25.0°C. What is Keg for this reaction?
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