Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
![### Organic Chemistry Reaction Guide
#### Reaction 7
**Starting Material:**
![Starting Material](https://latex.codecogs.com/png.image?\dpi{110}\bg{white}\mathrm{C_6H_5-COOCH_3})
**Reagents and Conditions:**
1) DIBAL
2) H₂O
**Description:**
This reaction involves the use of Diisobutylaluminum hydride (DIBAL) followed by hydrolysis. DIBAL is a selective reducing agent that can reduce esters to aldehydes under controlled conditions.
----
#### Reaction 8
**Starting Material:**
![Starting Material](https://latex.codecogs.com/png.image?\dpi{110}\bg{white}\mathrm{Cl-C_6H_4-CH_2CH_2OH})
**Reagents and Conditions:**
CrO₃, H₂SO₄/H₂O
**Description:**
This reaction utilizes chromium trioxide (CrO₃) in a mixture of sulfuric acid and water, known as Jones' reagent, to oxidize the primary alcohol to a carboxylic acid.
----
#### Reaction 9
**Starting Material:**
![Starting Material](https://latex.codecogs.com/png.image?\dpi{110}\bg{white}\mathrm{CH_3CH_2CHBrCH_3})
**Reagents and Conditions:**
1) Ph₃P
2) n-butyllithium
**Products:**
- Product 1: Alkene
- Product 2: Aldehyde
**Description:**
This reaction sequence involves the Wittig reaction, where triphenylphosphine (Ph₃P) and n-butyllithium are used to form an ylide from the bromoalkane, leading to the formation of an alkene and subsequently an aldehyde.
----
#### Reaction 10
**Starting Material:**
![Starting Material](https://latex.codecogs.com/png.image?\dpi{110}\bg{white}\mathrm{C_6H_5COCH_2CH_3})
**Reagents and Conditions:**
1) CH₃CH₂MgBr
2) H₂O
**Description:**
This reaction involves the use of a Grignard reagent (CH₃CH₂MgBr) which adds to the carbonyl group forming an alcohol upon aqueous workup.
----](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F0c5e7922-d36a-4f7e-a10b-c3fa062a9dc8%2F7d9f7c90-0a7f-470b-b8e2-8921126dcb61%2Feryyl9j_processed.jpeg&w=3840&q=75)
Transcribed Image Text:### Organic Chemistry Reaction Guide
#### Reaction 7
**Starting Material:**
![Starting Material](https://latex.codecogs.com/png.image?\dpi{110}\bg{white}\mathrm{C_6H_5-COOCH_3})
**Reagents and Conditions:**
1) DIBAL
2) H₂O
**Description:**
This reaction involves the use of Diisobutylaluminum hydride (DIBAL) followed by hydrolysis. DIBAL is a selective reducing agent that can reduce esters to aldehydes under controlled conditions.
----
#### Reaction 8
**Starting Material:**
![Starting Material](https://latex.codecogs.com/png.image?\dpi{110}\bg{white}\mathrm{Cl-C_6H_4-CH_2CH_2OH})
**Reagents and Conditions:**
CrO₃, H₂SO₄/H₂O
**Description:**
This reaction utilizes chromium trioxide (CrO₃) in a mixture of sulfuric acid and water, known as Jones' reagent, to oxidize the primary alcohol to a carboxylic acid.
----
#### Reaction 9
**Starting Material:**
![Starting Material](https://latex.codecogs.com/png.image?\dpi{110}\bg{white}\mathrm{CH_3CH_2CHBrCH_3})
**Reagents and Conditions:**
1) Ph₃P
2) n-butyllithium
**Products:**
- Product 1: Alkene
- Product 2: Aldehyde
**Description:**
This reaction sequence involves the Wittig reaction, where triphenylphosphine (Ph₃P) and n-butyllithium are used to form an ylide from the bromoalkane, leading to the formation of an alkene and subsequently an aldehyde.
----
#### Reaction 10
**Starting Material:**
![Starting Material](https://latex.codecogs.com/png.image?\dpi{110}\bg{white}\mathrm{C_6H_5COCH_2CH_3})
**Reagents and Conditions:**
1) CH₃CH₂MgBr
2) H₂O
**Description:**
This reaction involves the use of a Grignard reagent (CH₃CH₂MgBr) which adds to the carbonyl group forming an alcohol upon aqueous workup.
----
Expert Solution
![](/static/compass_v2/shared-icons/check-mark.png)
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
Step by step
Solved in 2 steps with 1 images
![Blurred answer](/static/compass_v2/solution-images/blurred-answer.jpg)
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
![Principles of Instrumental Analysis](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
![Principles of Instrumental Analysis](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
![Organic Chemistry](https://www.bartleby.com/isbn_cover_images/9780078021558/9780078021558_smallCoverImage.gif)
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
![Chemistry: Principles and Reactions](https://www.bartleby.com/isbn_cover_images/9781305079373/9781305079373_smallCoverImage.gif)
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
![Elementary Principles of Chemical Processes, Bind…](https://www.bartleby.com/isbn_cover_images/9781118431221/9781118431221_smallCoverImage.gif)
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY