Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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
Transcribed Image Text:1-5
Identify the weakest carbon-hydsogen bond in the following diene?
1)
3)
H H
H;C
H;C 4 H
CH
4)
2)
1-6
Which one of the following is not tme concerning Diels-Alder reactions?
1) The reaction is stereospecific.
2) The reaction mechanism has only one step.
3) The reaction mechanism involves a resonance stabilized carbocation.
4) The diene must be a conjugated diene.
1-7
Identify the diene used in the reaction shown below.
heat
CH,
CN
H,C
+
diene
HC,
CH,
CH2
HC
H;C
CH3
CH
CH
1)
2)
3)
4)
1-8
What is product of the following Diels-Alder reaction?
CH;
CH;O,C
CO,CH;
heat
H.
H
H;C.
Co,CH3
H;C
CO,CH3
1)
3)
Co,CH3
CO,CH;
+ enantiomer
+ enantiomer
H;C,
co,CH3
H;C.
co,CH3
2)
4)
"CO,CH3
Co,CH3
+ enantiomer

Transcribed Image Text:1
Which is most acidic hydrocarbon?
1)
2)
3)
4)
What is product of the following Diels-Alder reaction?
CH3
CH;O,C
Co,CH3
heat
H
н
H;C.
CO,CH;
H;C.
.CO,CH3
1)
3)
Co,CH;
Co,CH3
+ enantiomer
+ enantiomer
H;C.
Co,CH;
H;C.
Co,CH;
2)
4)
"CO,CH;
CO̟CH;
+ enantiomer
Which of the following dienes would you expect to be the most reactive in Diels-Alder
reactions?
A)
B)
N-H
D)
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